FeCl2-catalyzed hydroboration of aryl alkenes with bis(pinacolato) diboron

Liu Yang; Zhou Yuhan; Wang Huan; Qu Jingping

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FeCl2-catalyzed hydroboration of aryl alkenes with bis(pinacolato) diboron

机译：FeCl2催化双（频哪醇）二硼烷芳烃加氢硼化

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The first ligand-free ferrous chloride catalyzed anti-Markovnikov hydroboration of un-activated aryl alkenes with bis(pinacolato) diboron (B(2)pin(2)) has been reported. The reactions proceeded smoothly with high regioselectivity for a large range of aryl alkenes with wide functional-group compatibility and low catalyst loading under mild conditions.

机译：据报道，第一个不含配体的氯化亚铁催化了未活化的芳基烯烃与双（频哪醇）二硼（B（2）pin（2））的反马尔科夫尼科夫硼氢化反应。对于温和条件下具有宽泛的官能团相容性和低催化剂负载量的各种芳基烯烃，反应以高的区域选择性平稳进行。

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《RSC Advances》 |2015年第90期|共9页
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Liu Yang; Zhou Yuhan; Wang Huan; Qu Jingping;
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正文语种 eng
中图分类化学;
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1. FeCl2-catalyzed hydroboration of aryl alkenes with bis(pinacolato) diboron [J] . Liu Yang, Zhou Yuhan, Wang Huan, RSC Advances . 2015,第90期

机译：FeCl2催化双（频哪醇）二硼烷芳烃加氢硼化
2. Selective Synthesis of Secondary Alkylboronates: Markovnikov-Selective Hydroboration of Vinylarenes with Bis(pinacolato)diboron Catalyzed by a Nickel Pincer Complex [J] . Hashimoto Toru, Shiota Keisuke, Yamaguchi Yoshitaka Organic letters . 2020,第10期

机译：二次烷基硼的选择性合成：用镍钳络合物催化的双（Pinacolato）二硼酮的乙烯基的Markovnikov选择性水
3. Copper/Bisphosphine Catalysts in the Internally Borylative Aminoboration of Unactivated Terminal Alkenes with Bis(pinacolato)diboron [J] . Kato Kodai, Hirano Koji, Miura Masahiro The Journal of Organic Chemistry . 2017,第19期

机译：铜/二膦催化剂在核心邻氨基氨基中与双（Pinacolato）二硼（Pinacolato）二硼烯
4. Development of Chiral Bisphosphine Ligand Design Method for Copper(I)-catalyzed Enantioselective Markovnikov Hydroboration of Aliphatic Terminal Alkenes [C] . Hiroaki Iwamoto, Tsuneo Imamoto, Hajime Ito 日本化学会春季年会講演予稿集 . 2018

机译：用于铜（I）的手性双膦配体设计方法的开发 - 催化脂族末端烯烃的映射性Markovnov水合液
5. Transition Metal Catalyzed Enantioselective Hydroboration and Hydrovinylation of Alkenes [D] . Duvvuri, Krishnaja 2018

机译：过渡金属催化烯烃的对映选择性硼氢化和氢乙烯基化
6. Diastereo- and Enantioselective Reactions of Bis(pinacolato)diboron13-Enynes and Aldehydes Catalyzed by an Easily Accessible Bisphosphine–CuComplex [O] . Fanke Meng, Fredrik Haeffner, Amir H. Hoveyda, -1

机译：双（频哪醇）双硼的非对映和对映选择性反应容易获得的双膦-铜催化13-烯类和醛类复杂
7. Diboration of alkenes with bis(pinacolato)diboron catalysed by a platinum(0) complex [O] . Ishiyama, Tatsuo, Yamamoto, Masafumi, Miyaura, Norio 1997

机译：铂（0）配合物催化双（频哪醇）二硼烷对烯烃的硼化
8. Ground States of Molecules. 46. MNDO Study of Hydroboration of Alkenes and Alkynes. [R] . Dewar, M. J. S., McKee, M. L. 1977

机译：分子的基态。 46. mNDO烯烃和炔烃的硼氢化研究。

FeCl2-catalyzed hydroboration of aryl alkenes with bis(pinacolato) diboron

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