Aqueous formic acid: an efficient, inexpensive and environmentally friendly organocatalyst for three-component Strecker synthesis of alpha-aminonitriles and imines with excellent yields

Ghafuri Hossein; Roshani Mahdi

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Aqueous formic acid: an efficient, inexpensive and environmentally friendly organocatalyst for three-component Strecker synthesis of alpha-aminonitriles and imines with excellent yields

机译：甲酸水溶液：高效，廉价且环保的有机催化剂，用于三组分Strecker合成α-氨基腈和亚胺，产率高

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Aqueous formic acid (37%) which is an efficient, inexpensive and environmentally friendly organocatalyst was used in the Strecker reaction to afford alpha-aminonitriles and imines. Reaction was carried out under mild conditions and room temperature in high yields. We obtained alpha-aminonitrile derives by using trimethylsilyl cyanide through the Strecker reaction. The most important feature of formic acid as a catalyst is affordability and availability.

机译：在Strecker反应中使用了高效，廉价且环保的有机催化剂甲酸水溶液（37％），得到α-氨基腈和亚胺。反应在温和的条件和室温下以高产率进行。我们通过Strecker反应使用三甲基甲硅烷基氰化物获得了α-氨基腈衍生物。甲酸作为催化剂的最重要特征是可负担性和可利用性。

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《RSC Advances》 |2014年第102期|共7页
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Ghafuri Hossein; Roshani Mahdi;
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1. Aqueous formic acid: an efficient, inexpensive and environmentally friendly organocatalyst for three-component Strecker synthesis of alpha-aminonitriles and imines with excellent yields [J] . Ghafuri Hossein, Roshani Mahdi RSC Advances . 2014,第102期

机译：甲酸水溶液：高效，廉价且环保的有机催化剂，用于三组分Strecker合成α-氨基腈和亚胺，产率高
2. Formic acid catalyzed one-pot synthesis of alpha-aminophosphonates: an efficient, inexpensive and environmental friendly organocatalyst [J] . Mehraban Jamshid Azarnia, Jalali Mahsa Sadat, Heydari Akbar Chemicke Zvesti . 2018,第9期

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Aqueous formic acid: an efficient, inexpensive and environmentally friendly organocatalyst for three-component Strecker synthesis of alpha-aminonitriles and imines with excellent yields

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