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Solvothermal synthesis and visible light-driven photocatalytic degradation for tetracycline of Fe-doped SrTiO3

机译:Fe掺杂SrTiO3四环素的溶剂热合成和可见光驱动的光催化降解

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摘要

In this paper, Fe-doped SrTiO3 (FSTO) photocatalysts were successfully prepared via a facile solvothermal method, and their photocatalytic activities for degrading tetracycline (TC) under visible light irradiation were examined. It was found that doping Fe3+ into the lattice of SrTiO3 resulted in the formation of new absorption bands in the visible light region, and the energy band gap decreased from 3.2 eV to 2.6 eV with Fe3+ doping amounts of 0 to 5 wt%. The photocatalytic experimental results indicated that the as-prepared FSTO photocatalysts generate an extremely high enhancement in the TC degradation ratio compared to the pure SrTiO3 under visible light irradiation. In particular, the FSTO sample doped with 3% Fe exhibited the highest TC degradation ratio (71.6%) in 80 min, which is mainly attributed to the narrowed gap generated by the appropriate level of Fe3+ doping. This work suggests that this doping method should be applicable for exploiting other efficient visible light-driven photocatalysts with wide band gap semiconductors.
机译:本文采用一种简便的溶剂热法成功制备了Fe掺杂的SrTiO3(FSTO)光催化剂,并研究了其在可见光照射下降解四环素(TC)的光催化活性。发现将Fe 3+掺杂到SrTiO 3的晶格中导致在可见光区域中形成新的吸收带,并且当Fe 3+的掺杂量为0至5wt%时,能带隙从3.2eV降低至2.6eV。光催化实验结果表明,与纯SrTiO3在可见光照射下相比,所制备的FSTO光催化剂产生的TC降解率极高的提高。特别是,掺有3%Fe的FSTO样品在80分钟内表现出最高的TC降解率(71.6%),这主要归因于适当水平的Fe3 +掺杂所产生的间隙变窄。这项工作表明这种掺杂方法应适用于利用宽带隙半导体开发其他有效的可见光驱动光催化剂。

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