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The effect of a thin gold layer on graphene: a Raman spectroscopy study

机译:薄金层对石墨烯的影响:拉曼光谱研究

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摘要

An understanding of interactions between graphene and its surroundings is crucial for application of graphene in electronic devices. Raman spectroscopy is a convenient and efficient tool to provide information about the doping, stress and defects in graphene; however application of this method is limited to the Si/SiO2 substrate which provides interference enhancement. Here we present a comprehensive Raman study of the single-layer graphene - sapphire - gold system. Due to plasmons generated in the gold-layer the Raman signal of graphene is significantly enhanced. We study the influence of the gold layer thickness and gold particle size on the enhancement. The analysis of the Raman maps showed that graphene on sapphire is only slightly doped and the spatial distribution of doping is quite homogenous. Also no significant strain was generated in graphene sandwiched by sapphire and gold.
机译:对石墨烯及其周围环境之间相互作用的理解对于石墨烯在电子设备中的应用至关重要。拉曼光谱法是一种方便有效的工具,可提供有关石墨烯中掺杂,应力和缺陷的信息。然而,该方法的应用限于提供干涉增强的Si / SiO 2衬底。在这里,我们介绍了对单层石墨烯-蓝宝石-金系统的全面拉曼研究。由于在金层中产生等离激元,因此石墨烯的拉曼信号显着增强。我们研究了金层厚度和金粒度对增强的影响。拉曼图的分析表明,蓝宝石上的石墨烯仅被轻度掺杂,并且掺杂的空间分布非常均匀。在蓝宝石和金夹层的石墨烯中也没有产生明显的应变。

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