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Functionalization of aerogels by the use of pre-constructed monomers: the case of trifluoroacetylated (3-aminopropyl) triethoxysilane

机译:使用预制单体对气凝胶进行功能化:三氟乙酰化(3-氨基丙基)三乙氧基硅烷的情况

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摘要

A novel strategy for aerogels' functionalization, based on the preliminary modification of monomers before gelation, is proposed. The strategy is illustrated by the synthesis of trifluoroacetylated (3-aminopropyl) triethoxysilane (APTES)-based aerogels. An aerogel sample prepared by cogelation of APTES with tetraethoxysilane (TEOS), followed by trifluoroacetylation of free aminogroups, had a BET-surface area of 100-180 m(2) g(-1), while the samples prepared by cogelation of a preliminary trifluoroacetylated monomer with TEOS had a 2-5 times larger specific surface area. Trifluoroacetylated aerogels' properties showed strong dependence on the supercritical drying media.
机译:提出了一种基于凝胶化之前对单体进行初步修饰的气凝胶功能化的新策略。通过合成基于三氟乙酰化(3-氨基丙基)三乙氧基硅烷(APTES)的气凝胶可以说明该策略。通过将APTES与四乙氧基硅烷(TEOS)凝胶化,然后对游离氨基进行三氟乙酰化,制备的气凝胶样品的BET表面积为100-180 m(2)g(-1),而通过初步凝胶化制备的样品具有TEOS的三氟乙酰化单体的比表面积大2-5倍。三氟乙酰化气凝胶的性能显示出对超临界干燥介质的强烈依赖性。

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