Nitrogen-rich carbonaceous two-dimensional polymers were prepared through dynamic covalent chemistry under ionthermal conditions. The synthesis is based on the formation of 2D polytriazine networks via the polytrimerization of nitriles of 2,4,6-tricyano-1,3,5-triazine (TCT) monomers from ZnCl2 salt melts at 400 degrees C. The formation of the 2D polymer was verified by detailed characterization.
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