A two step protocol for the synthesis of highly substituted benzobicyclo[2.2.2]octadienone derivatives from 2-methoxyphenols

Chittimalla Santhosh Kumar; Bandi Chennakesavulu; Putturu Sireesha

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A two step protocol for the synthesis of highly substituted benzobicyclo[2.2.2]octadienone derivatives from 2-methoxyphenols

机译：从2-甲氧基苯酚合成高度取代的苯并双环[2.2.2]辛二烯酮衍生物的两步方案

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摘要

A rapid process for the synthesis of functionally rich benzobicyclo [2.2.2]octadienone derivatives has been realized through oxidative dimerization of commercially/readily available 2-methoxyphenols followed by an aromatization sequence.

机译：通过将市售/容易获得的2-甲氧基苯酚进行氧化二聚，然后进行芳构化顺序，已经实现了一种功能丰富的苯并双环[2.2.2]辛二烯酮衍生物的快速合成方法。

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《RSC Advances》 |2015年第11期|共6页
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Chittimalla Santhosh Kumar; Bandi Chennakesavulu; Putturu Sireesha;
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中图分类化学;
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1. A two step protocol for the synthesis of highly substituted benzobicyclo[2.2.2]octadienone derivatives from 2-methoxyphenols [J] . Chittimalla Santhosh Kumar, Bandi Chennakesavulu, Putturu Sireesha RSC Advances . 2015,第11期

机译：从2-甲氧基苯酚合成高度取代的苯并双环[2.2.2]辛二烯酮衍生物的两步方案
2. One-pot multicomponent synthesis of highly substituted bicyclo[2.2.2]octane derivatives using bismuth nitrate as a catalyst [J] . Gein Vladimir L., Yankin Andrei N., Nosova Natalia V., Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2016,第22期

机译：以硝酸铋为催化剂一锅多组分合成高度取代的双环[2.2.2]辛烷衍生物
3. A highly efficient and aerobic protocol for the synthesis of N-heteroary1 substituted 9-arylcarbazolyl derivatives via a palladium-catalyzed ligand-free Suzuki reaction [J] . Xiaofeng Rao, Chun Liu, Jieshan Qiu, Organic & biomolecular chemistry . 2012,第39期

机译：通过钯催化的无配体Suzuki反应合成N-杂芳基1取代的9-芳基咔唑基衍生物的高效好氧方案
4. Synthesis and Optoelectronic Properties of 2,2,3,3,5,5,6,6,7,7,8,8-Dodecamethyl-2,3,5,6,7,8-hexasilabicyclo2.2.2octane-l-yl-substituted Pyrans [C] . Masaki Shimizu, Tamejiro Hiyama, Emiko Hagiwara Symposium on Organometallic Chemistry . 2004

机译：2,2,3,3,5,5,6,6,7,8,8-十二烷甲基-2,3,5,6,7,8-己基硅酰亚乙基 - 辛烷值的合成和光电性能2.2.2辛烷值-L-YL-取代的血臼
5. I. SYNTHETIC APPROACHES TO SUBSTITUTED 2-OXABICYCLO(3.2.1)OCTANE DERIVATIVES AND II. THE SYNTHESIS OF 1-SUBSTITUTED DERIVATIVES OF ANHYDRO (3-CHLOROACETYL-2-HYDROXYIMIDAZO(1,2-A)PYRIDINIUM HYDROXIDE). [D] . FRIEDMAN, ALAN E. 1973

机译：I.取代2-氧杂双环（3.2.1）正己烷衍生物的合成方法和II。合成1-取代的酸酐（3-氯乙酰基-2-羟基咪唑并（1,2-A）吡啶鎓氢氧化物）。
6. One Step Continuous Flow Synthesis of Highly Substituted Pyrrole-3-Carboxylic Acid Derivatives via in situ Hydrolysis of tert-Butyl Esters [O] . Ananda Herath, Nicholas D. P. Cosford -1

机译：通过原位叔丁基酯水解高度取代的吡咯-3-羧酸衍生物的一步法连续流动合成
7. Domino retro Diels-Alder/Diels-Alder reaction: An efficient protocol for the synthesis of highly functionalized bicyclo2.2.2octenones and bicyclo2.2.2octadienones [O] . ChittimallaSanthosh Kumar 2011

机译：多米诺复古Diels-Alder / Diels-Alder反应：合成高度官能化的双环2.2.2辛烯酮和双环2.2.2辛二烯酮的有效方法

A two step protocol for the synthesis of highly substituted benzobicyclo[2.2.2]octadienone derivatives from 2-methoxyphenols

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