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Individual photoreorientation of non-aggregated and aggregated azobenzene side chains tethered to a liquid-crystalline polymer determined by higher order derivative spectra

机译:非聚集和聚集的偶氮苯侧​​链束缚在液晶聚合物上的单个光取向由高阶导数光谱确定

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摘要

Higher order derivative spectra were applied to UV-VIS spectral changes of a liquid-crystalline polymer with azobenzene side chains exposed to linearly polarised 436 nm light at an elevated temperature to reveal the participation of non-aggregated as well as two types of aggregated species in in-plane as well as out-of-plane photoreorientation individually.
机译:将高阶导数光谱应用于在高温下偶氮苯侧链暴露于线性偏振436 nm光的液晶聚合物的UV-VIS光谱变化,以揭示非聚集态和两种类型聚集态物种的参与。平面内和平面外光重新定向。

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