Formation of a charge transfer complex within a hydrophobic cavity in DNA

Takada Tadao; Otsuka Yumiko; Nakamura Mitsunobu; Yamana Kazushige

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Formation of a charge transfer complex within a hydrophobic cavity in DNA

机译：在DNA的疏水腔内形成电荷转移复合物

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We now show that a hydrophobic cavity created within the DNA can work as a scaffold to form a charge transfer (CT) complex composed of naphthalenediimide (NDI) and dialkoxynaphthalene (DAN) derivatives. The formation of the CT complex resulted in stabilization of the duplex structure through stacking interaction, which was comparable to the natural base pairs.

机译：现在我们显示出在DNA中产生的疏水腔可以作为支架形成由萘二甲酰亚胺（NDI）和二烷氧基萘（DAN）衍生物组成的电荷转移（CT）复合物。 CT复合物的形成导致通过堆叠相互作用使双链体结构稳定，这与天然碱基对相当。

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《RSC Advances》 |2014年第103期|共4页
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Takada Tadao; Otsuka Yumiko; Nakamura Mitsunobu; Yamana Kazushige;
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中图分类化学;
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1. Formation of a charge transfer complex within a hydrophobic cavity in DNA [J] . Takada Tadao, Otsuka Yumiko, Nakamura Mitsunobu, RSC Advances . 2014,第103期

机译：在DNA的疏水腔内形成电荷转移复合物
2. Constrained photophysics of partially and fully encapsulated charge transfer probe (E)-3-(4-Methylaminophenyl) acrylic acid methyl ester inside cyclodextrin nano-cavities: Evidence of cyclodextrins cavity dependent complex stoichiometry [J] . Ghosh S., Jana S., Guchhait N. Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2011,第Null期

机译：部分和完全包封的电荷转移探针（E）-3-（4-甲基氨基苯基）丙烯酸甲酯在环糊精纳米腔内部的受约束的光物理：环糊精腔依赖的复杂化学计量的证据
3. Effects of Polyelectrolytes on the Charge Transfer Complexing between Indole derivatives and Methylviologen: Hydrophobic and Electrostatic Interactions [J] . Book Kee Hwang, Joon Woo Park Bulletin of the Korean Chemical Society . 1985,第3期

机译：聚电解质对吲哚衍生物与甲基紫精之间电荷转移络合的影响：疏水和静电相互作用
4. Charge Transfer in DNA-Metal-Ligand Complexes. Polynucleotides [C] . N. S. Fialko, V. D. Lakhno NATO Advanced Study Institute on Metal-Ligand Interactions: Molecular-, Nano-, Micro-, and Macro-Systems in Complex Environments . 2003

机译：在DNA-金属配体配合物中的电荷转移。多核苷酸
5. (1) Flipped-out and switched-on ionophores. (2) Conformationally controlled intramolecular charge transfer complexes. (3) Intramolecular charge transfer ionophores [D] . Durocher, David Thomas. 1990

机译：（1）翻转并打开离子载体。（2）构象控制的分子内电荷转移复合物。（3）分子内电荷转移离子载体
6. Charge-based Interaction Conserved within Histone H3 Lysine 4 (H3K4) Methyltransferase Complexes Is Needed for Protein Stability Histone Methylation and Gene Expression [O] . Douglas P. Mersman, Hai-Ning Du, Ian M. Fingerman, 2012

机译：蛋白质稳定组蛋白甲基化和基因表达需要组蛋白H3赖氨酸4（H3K4）甲基转移酶复合物中保守的基于电荷的相互作用
7. Charge-transfer and Proton-transfer in the Formation of Molecular Complexes. XI. Phase Transitions in Hertel’s Picric Acid Complexes [O] . Yoshio Matsunaga, Eiji Osawa, Ryuzo Osawa 1975

机译：在分子复合物形成中的电荷转移和质子转移。 XI。 Hertel的Piccric acid综合体中的相变

Formation of a charge transfer complex within a hydrophobic cavity in DNA

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