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On the graphene incorporated LiMn2O4 nanostructures: possibilities for tuning the preferred orientations and high rate capabilities

机译:在掺有石墨烯的LiMn2O4纳米结构上:调整优选取向和高倍率能力的可能性

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摘要

Nano-material synthesis (here: LiMn2O4) carried out in the presence of graphene nano-sheets is shown using a crystal shape algorithm to be preferentially oriented along the thermodynamically stable (400) direction, indicating that graphene controls the synthesis through a thermo-dynamical step. Electrochemical studies show that the cathode material with preferred orientation along the (400) direction possesses superior electrochemical properties in general and much better rate capability in particular.
机译:使用晶体形状算法显示在石墨烯纳米片存在下进行的纳米材料合成(此处为LiMn2O4)优先沿热力学稳定(400)方向取向,表明石墨烯通过热力学控制合成步。电化学研究表明,沿(400)方向具有优选取向的阴极材料通常具有优异的电化学性能,尤其是具有更好的倍率性能。

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