Mn(OAc)(3)-mediated synthesis of beta-hydroxyphosphonates from P(O)-H compounds and alkenes

Gao Yuzhen; Wu Ju; Xu Jian; Zhang Pengbo; Tang Guo; Zhao Yufen

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Mn(OAc)(3)-mediated synthesis of beta-hydroxyphosphonates from P(O)-H compounds and alkenes

机译：Mn（OAc）（3）介导的由P（O）-H化合物和烯烃合成β-羟基膦酸酯

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摘要

A new and general method for the synthesis of beta-hydroxy phosphonates has been achieved through Mn(OAc)(3)-mediated radical oxidative phosphonation of alkenes with H-phosphonates and H-phosphine oxide. The starting materials of P(O)-H compounds and alkenes are stable and cheap. Mn(OAc)(3) can be readily prepared from Mn(OAc)(2) in the laboratory. This method can be easily adapted to large-scale preparations.

机译：通过Mn（OAc）（3）介导的烯烃与H-膦酸酯和H-膦氧化物的自由基氧化膦化反应，已实现了合成β-羟基膦酸酯的新方法。 P（O）-H化合物和烯烃的起始原料稳定且便宜。 Mn（OAc）（3）在实验室中可以很容易地从Mn（OAc）（2）制备。该方法可轻松适用于大规模制备。

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《RSC Advances》 |2014年第93期|共4页
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Gao Yuzhen; Wu Ju; Xu Jian; Zhang Pengbo; Tang Guo; Zhao Yufen;
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正文语种 eng
中图分类化学;
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1. Mn(OAc)(3)-mediated synthesis of beta-hydroxyphosphonates from P(O)-H compounds and alkenes [J] . Gao Yuzhen, Wu Ju, Xu Jian, RSC Advances . 2014,第93期

机译：Mn（OAc）（3）介导的由P（O）-H化合物和烯烃合成β-羟基膦酸酯
2. Mn(OAc) _3-promoted sulfur-directed addition of an active methylene compound to alkenes [J] . Deliomeroglu M.K., Dengiz C., ?al?kan R., Tetrahedron . 2012,第29期

机译：Mn（OAc）_3促进的活性亚甲基化合物硫定向加成到烯烃中
3. Mn(OAc)(3)-Mediated Hydrotrifluoromethylation of Unactivated Alkenes Using CF3SO2Na as the Trifluoromethyl Source [J] . Cui Bin, Sung Hui, Xu Yibo, The Journal of Organic Chemistry . 2018,第11期

机译：使用CF3SO2NA作为三氟甲基源的Mn（3）介导的肼二氟甲基化。
4. Organocopper-mediated stereoselective synthesis of multi-substituted alkene dipeptides isosteres and application to cyclic RDG peptides [C] . Shinya Oishi, Takae Kamano, Ayumu Niida, European Peptide Symposium . 2002

机译：有机缺陷介导的多取代烯烃二肽旁观者的立体选择性合成及其在环rdg肽的应用
5. Manganese triacetate-mediated oxidative and dehydrative cyclizations of nitroacetate esters; manganese triacetate-mediated lactonization of chloro- and dichloro-acetic acid with alkenes; total synthesis of (+/-)-cladobotryal, (+/-)-CJ16,169 and (+/-)-CJ16,170; synthesis of (+/-)-deoxysymbioimine. [D] . Che, Qinglin. 2006

机译：三乙酸锰介导的硝基乙酸酯的氧化和脱水环化；三乙酸锰介导的氯乙酸和二氯乙酸与烯烃的内酯化；（+/-）-锁骨肌，（+/-）-CJ16,169和（+/-）-CJ16,170的总合成; （+/-）-脱氧共生亚胺的合成。
6. Synthesis and characterization of piperazine-substituted dihydrofuran derivatives viaMn(OAc)3mediated radical cyclizations [O] . Sait SARI, Mehmet YILMAZ 2020

机译：哌嗪取代二氢呋喃衍生物的合成与表征ViaMN（OAC）3.介导的自由基环化
7. Mn(OAc)3-mediated synthesis of β-hydroxyphosphonates from P(O)-H compounds and alkenes [O] . Gao Yuzhen, Wu Ju, Xu Jian, 2014

机译：Mn（OAc）3介导的P（O）-H化合物和烯烃合成β-羟基膦酸酯

Mn(OAc)(3)-mediated synthesis of beta-hydroxyphosphonates from P(O)-H compounds and alkenes

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