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Bi2S3 nanorods modified with Co(OH)(2) ultrathin nanosheets to significantly improve its pseudocapacitance for high specific capacitance

机译:Co(OH)(2)超薄纳米片修饰的Bi2S3纳米棒,可显着提高其伪电容以获得高比电容

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Nanostructured Bi2S3 has been used in various energy conversion and storage systems, but it alone does not possess significant capacitance and this has never been investigated. A modification at the nanoscale is used to create a structure composed of Bi2S3 nanorods and alpha-Co(OH)(2) nanosheets, which is controllably synthesized by a facile seed-layer assisted hydrothermal method to produce the former followed by electrochemical deposition of the latter. The Co(OH)(2)-modified Bi2S3 nanorods significantly boost the pseudocapacitance of Bi2S3 for high specific capacitance, while improving the cycle life stability. Results reveal that the controlled Co(OH)(2) modification process promotes a networked, highly porous structure for a considerably larger surface allowing the electrolyte-access; thus, enhancing the pseudocapacitance and resulting in a high specific capacitance.
机译:纳米结构的Bi2S3已用于各种能量转换和存储系统中,但仅其本身并不具有显着的电容,因此从未进行过研究。纳米级的修饰用于创建由Bi2S3纳米棒和α-Co(OH)(2)纳米片组成的结构,该结构通过一种简便的种子层辅助水热法可控制地合成,以产生前者,然后对其进行电化学沉积。后者。 Co(OH)(2)修饰的Bi2S3纳米棒显着提高了Bi2S3对于高比电容的假电容,同时提高了循环寿命的稳定性。结果表明,受控的Co(OH)(2)修饰过程可促进网络化,高度多孔的结构,从而获得更大的表面,从而允许电解质进入。因此,增强了伪电容并导致了高的比电容。

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