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A facile dip-coating approach to stable superhydrophobic SiO2/epoxy resin membrane preparation for micro-water separation in transformer oil liquids

机译:一种简便的浸涂法,用于稳定的超疏水SiO2 /环氧树脂膜的制备,用于变压器油液中的微水分离

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摘要

In this study, a facile one-step dip-coating approach was reported for superhydrophobic membrane fabrication, in which only epoxy resin and silica nanoparticles were needed. In addition, the surface microstructure and wettability of the membrane were closely related to the content of silica nanoparticles. When the content of silica nanoparticles was 4 wt%, the membrane exhibited optimum surface roughness and superhydrophobicity, by which water was blocked, while oil was allowed to permeate. Through the application of water contact angle, scanning electron microscopy, energy dispersive spectroscopy, thermal gravimetric analysis and Karl Fischer moisture titrator measurements, the membrane examination indicated that the microanostructures enhanced the water repellency, which was similar to the lotus leaf effect. Furthermore, this method is suitable for large-scale production and employed for micro-water separation in transformer oil. This is possible because environmentally friendly and inexpensive materials are adopted and harsh operations, sophisticated equipment and a special atmosphere are avoided.
机译:在这项研究中,报道了一种用于超疏水膜制造的简便的一步浸涂方法,该方法仅需要环氧树脂和二氧化硅纳米粒子。另外,膜的表面微观结构和润湿性与二氧化硅纳米颗粒的含量密切相关。当二氧化硅纳米颗粒的含量为4重量%时,膜表现出最佳的表面粗糙度和超疏水性,由此水被阻隔,而油则渗透。通过应用水接触角,扫描电子显微镜,能量色散光谱,热重分析和卡尔·费休水分滴定仪测量,膜检查表明,微观/纳米结构增强了拒水性,这类似于荷叶效应。此外,该方法适用于大规模生产,并用于变压器油中的微量水分离。这是可能的,因为采用了环保且廉价的材料,避免了苛刻的操作,复杂的设备和特殊的气氛。

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