n-Alkane isomerization on heteropolyacids 1.The influence of acid-base properties of alumina systems on the state of supported 12-tungstophosphoric heterop

A.V.Ivanov; T.V.Vasina; O.V.Masloboishchikova; E.G.Khelkovskaya-Sergeeva; L.M.Kustov; J.I.Houzvicka

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n-Alkane isomerization on heteropolyacids 1.The influence of acid-base properties of alumina systems on the state of supported 12-tungstophosphoric heterop

机译：杂多酸的正构烷烃异构化1.氧化铝体系的酸碱性质对负载的12-钨磷杂化物状态的影响

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Acid-base properties of bulk 12-bungstophosphoric heteropolyacid (HPWA) and HPWA supported on alumina and fluorinated alumina were studied by DRIFT spectroscopy using adsorption of probe molecules.Catalytic properties of Pt-containing catalysts carried by these supports were studied in n-pentane isomerization.It was shown that the Pt/HPWA/Al_2O_3 system is almost inactive in isomerization as a result of the interaction of HPWA with basic sites of the alumina support.On the contrary,the presence of acidic sites in fluorinated alumina prevents HPWA destruction and favors the uniform distribution of HPWA on the support surface.As a result,enhancenment of the activity and selectivity of the Pt/HPWA/Al_2O_3-F catalyst in n-pentane isomerization is observed.

机译：利用探针分子的吸附，通过DRIFT光谱研究了负载在氧化铝和氟化氧化铝上的12-笨重磷杂多酸（HPWA）和HPWA的酸碱性质;研究了这些载体负载的含Pt催化剂在正戊烷异构化中的催化性能。结果表明，由于HPWA与氧化铝载体碱性位点的相互作用，Pt / HPWA / Al_2O_3体系几乎没有活性。相反，氟化氧化铝中酸性位点的存在阻止了HPWA的破坏并有利于结果，观察到正戊烷异构化过程中Pt / HPWA / Al_2O_3-F催化剂活性和选择性的提高。

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《Russian Chemical Bulletin》 |2000年第10期|共6页
作者
A.V.Ivanov; T.V.Vasina; O.V.Masloboishchikova; E.G.Khelkovskaya-Sergeeva; L.M.Kustov; J.I.Houzvicka;
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正文语种 eng
中图分类化学;
关键词
heteropolyacids; 12-tungstophosphoric heteropolyacid; isomerization; n-pen-tane; platinum; adsorption; acidity; probe molecules; basicity; IR spectroscopy; DRIFT spectroscopy.;

机译：杂多酸;12-钨磷杂多酸;异构化;正戊烷;铂;吸附;酸度;探针分子;碱度;IR光谱;DRIFT光谱;

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1. n-Alkane isomerization on heteropolyacids 1.The influence of acid-base properties of alumina systems on the state of supported 12-tungstophosphoric heterop [J] . A.V.Ivanov, T.V.Vasina, O.V.Masloboishchikova, Russian Chemical Bulletin . 2000,第10期

机译：杂多酸的正构烷烃异构化1.氧化铝体系的酸碱性质对负载的12-钨磷杂化物状态的影响
2. Investigation of co-effect of 12-tungstophosphoric heteropolyacid, nickel citrate and carbon-coated alumina in preparation of NiW catalysts for HDS, HYD and HDN reactions [J] . Nikulshin P. A., Minaev P. P., Mozhaev A. V., Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications . 2015,第Null期

机译：研究12钨磷杂多酸，柠檬酸镍和碳包覆氧化铝在制备用于HDS，HYD和HDN反应的NiW催化剂中的协同作用
3. Isomerization-cracking of n-octane on catalysts based on heteropolyacid H3Pw12O40 and heteropolyacid supported on zirconia and promoted with Pt and Cs [J] . Badano Juan M., Benítez Viviana M., Manuale Debora L., Quimica nova . 2013,第7期

机译：正辛烷在杂多酸H3Pw12O40和负载在氧化锆上并由Pt和Cs促进的杂多酸的催化剂上的异构化裂解
4. DEALUMINATED MFI MATERIALS AS CATALYSTS FOR THE DIRECT HYDROXYLATION OF BENZENE WITH NITROUS OXIDE: INFLUENCE OF ACID-BASE AND TEXTURAL PROPERTIES [C] . Kollmer, F., Hausmann, International Zeolite Conference pt.C; 20040425-30; Cape Town(ZA) . 2004

机译：脱铝的MFI材料作为苯与一氧化二氮直接羟基氧化的催化剂：酸碱和质构性质的影响
5. Structural Characterization, Olefin Polymerization, and Arene Hydrogenation Properties of Group 4 Complexes Supported on Highly Acidic Sulfated Aluminas. [D] . Williams, Linda Ann. 2011

机译：高酸性硫酸盐氧化铝上负载的第4组配合物的结构表征，烯烃聚合和芳烃加氢性能。
6. Synthesis of Dimethyl Ether via CO2 Hydrogenation:Effect of the Drying Technique of Alumina on Properties and Performanceof Alumina-Supported Copper Catalysts [O] . Chalida Niamnuy, Pawanrat Prapaitrakul, Noppadol Panchan, 2020

机译：通过CO2加氢合成二甲醚：氧化铝干燥工艺对性能的影响氧化铝负载的铜催化剂
7. Isomerization-cracking of n-octane on catalysts based on heteropolyacid H3Pw12O40 and heteropolyacid supported on zirconia and promoted with Pt and Cs [O] . Debora L. Manuale, Gerardo C. Torres, Viviana M. Benítez, 2013

机译：基于杂多酸H3pw12O40的催化剂上正辛烷的异构化裂解和负载在氧化锆上并用pt和Cs促进的杂多酸

n-Alkane isomerization on heteropolyacids 1.The influence of acid-base properties of alumina systems on the state of supported 12-tungstophosphoric heterop

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