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Preparation and Characterization of Biopolyols and Polyurethane Foams From Liquefied Faba Bean Stalk

机译:液化蚕豆茎中生物多元醇和聚氨酯泡沫的制备与表征

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摘要

In this study, Faba bean stalk was liquefied for the production of biopolyols and polyurethane (PU) foams. The influences of various reaction conditions on biopolyols and PU foams were examined. Furthermore, the property relationships between biopolyols and PU foams were investigated. Biopolyols produced under the liquefaction conditions of 160°C, 90 min, 3% sulfuric acid loading, and 20% Faba bean stalk loading showed promising material properties (i.e. hydroxyl number, 496.1 mg KOH/g, acid number, 17.9 mg KOH/g, and viscosity, 1.1 Pa.s). PU foams produced from promising biopolyols showed compressive strength of 205 kPa and density of 0.035 g/cm~3. The results suggested that in addition to density, the compressive strength of PU foams might also be affected by factors such as biomass residues or the chemical structures of biopolyols. The biopolyols and PU foams produced showed material properties comparable to those of conventional PU foams.
机译:在这项研究中,将蚕豆茎液化以生产生物多元醇和聚氨酯(PU)泡沫。考察了各种反应条件对生物多元醇和聚氨酯泡沫的影响。此外,研究了生物多元醇与PU泡沫之间的性能关系。在160°C,90分钟,3%的硫酸负载和20%的蚕豆秸秆负载的液化条件下生产的生物多元醇显示出令人鼓舞的材料性能(即羟值496.1 mg KOH / g,酸值17.9 mg KOH / g ,粘度为1.1 Pa.s)。由有前景的生物多元醇生产的PU泡沫的抗压强度为205 kPa,密度为0.035 g / cm〜3。结果表明,除了密度外,PU泡沫的抗压强度还可能受到生物质残留物或生物多元醇化学结构等因素的影响。所生产的生物多元醇和PU泡沫的材料性能可与常规PU泡沫相比。

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