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首页> 外文期刊>Russian Metallurgy(Metally) >Thermodynamics of Carbon and Oxygen Solutions in Manganese Melts
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Thermodynamics of Carbon and Oxygen Solutions in Manganese Melts

机译:锰熔体中碳和氧溶液的热力学

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The thermodynamics of carbon and oxygen solutions in manganese melts is studied. An equation for the temperature dependence of the activity coefficient of carbon in liquid manganese is obtained (gamma_(C(Mn)) deg =-1.5966 + (1.0735 X 10~(-3))T). The temperature dependence of the Gibbs energy of the reaction of carbon dissolved in liquid manganese with the oxygen of manganese oxide is shown to be described by the equation DELTA G_T deg =375264 - 184.66T (J/mol). This reaction can noticeably be developed depending on the carbon content at temperatures of 1700-1800 deg C. The deoxidation ability of carbon in manganese melts is shown to be much lower than that in iron and nickel melts due to the higher affinity of manganese to both oxygen and carbon. Although the deoxidation ability of carbon in manganese melts increases with temperature, the process develops at rather high carbon contents in all cases.
机译:研究了锰熔体中碳和氧溶液的热力学。得到了液态锰中碳活度系数与温度的关系式(γ_(C(Mn))deg = -1.5966 +(1.0735 X 10〜(-3))T)。溶解在液态锰中的碳与氧化锰的氧的反应的吉布斯能量的温度依赖性由等式DELTA G_T deg = 375264-184.66T(J / mol)描述。根据温度在1700至1800摄氏度之间的碳含量,可以显着地进行该反应。由于锰对两种金属的亲和力更高,因此锰熔体中碳的脱氧能力远低于铁熔体和镍熔体中的碳。氧气和碳。尽管锰熔体中碳的脱氧能力会随着温度的升高而增加,但在所有情况下,该过程都是在相当高的碳含量下进行的。

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