Enthalpies of Mixing and Intermolecular Interactions in N,N-Dimethylformamide-Chloroform Systems at Temperatures Ranging between 288 and 308 K

A. V. Kustov; N. L. Smirnova; M. B. Berezin

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Enthalpies of Mixing and Intermolecular Interactions in N,N-Dimethylformamide-Chloroform Systems at Temperatures Ranging between 288 and 308 K

机译：N，N-二甲基甲酰胺-氯仿体系中288和308 K之间的混合焓和分子间相互作用

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The thermal effects of N,N-dimethylformamide (DMF) and chloroform (ChF) dissolution in the ChF-DMF system are calorimetrically determined at 288, 298, and 308 K over the range of compositions. The partial molar enthalpies of the components are also calculated, along with the values for the enthalpies of mixing. It is found that mixing is a strongly exothermic process and depends only slightly on temperature. The enthalpy parameters of double and triple interactions between DMF molecules in ChF, and between ChF molecules in DMF, are determined using virial expansions.

机译：在组成范围内，量热法在288、298和308 K上量热确定了ChF-DMF系统中N，N-二甲基甲酰胺（DMF）和氯仿（ChF）溶解的热效应。还计算组分的部分摩尔焓，以及混合焓的值。发现混合是强烈放热的过程，并且仅轻微地取决于温度。使用病毒扩增确定ChF中DMF分子之间以及DMF中ChF分子之间的两次和三次相互作用的焓参数。

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《Russian Journal of Physical Chemistry》 |2014年第1期|共3页
作者
A. V. Kustov; N. L. Smirnova; M. B. Berezin;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
DMF; chloroform; enthalpy of mixing; intermolecular interactions;

机译：DMF;氯仿;混合焓;分子间相互作用;

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1. Enthalpies of Mixing and Intermolecular Interactions in N,N-Dimethylformamide-Chloroform Systems at Temperatures Ranging between 288 and 308 K [J] . A. V. Kustov, N. L. Smirnova, M. B. Berezin Russian Journal of Physical Chemistry . 2014,第2aPta1期

机译：N，N-二甲基甲酰胺-氯仿体系中288和308 K之间的混合焓和分子间相互作用
2. Enthalpies of mixing and intermolecular interactions in the 1-octanol-dimethylformamide system at 298-318 K [J] . Smirnova N.L., Kustov A.V. Russian Journal of Physical Chemistry . 2013,第5期

机译：1-辛醇-二甲基甲酰胺体系中298-318 K时的混合焓和分子间相互作用
3. Studies on intermolecular interaction on binary mixtures of methyl orange-water system: Excess molar functions of ultrasonic parameters at different concentrations and at different temperatures [J] . Thanuja B., Kanagam C., Sreedevi S. Ultrasonics sonochemistry . 2011,第6期

机译：甲基橙-水系统二元混合物的分子间相互作用研究：不同浓度和温度下超声参数的过量摩尔函数
4. TOWARDS THE ROLE OF THE RANGE OF INTERMOLECULAR INTERACTIONS: Systematic computer simulations of the fluids with electrostatic interactions [C] . I. Nezbeda, J. Kolafa, NATO NATO Advanced Research Workshop on Ionic Soft Matter: Modern Trends in Theory and Applications . 2005

机译：朝着分子间相互作用范围的作用：静电相互作用的系统计算机仿真
5. Part I. Picosecond optical calorimetry: Separating enthalpy and volume contributions, and determining absolute enthalpies from investigations of mixtures. Part II. Spectroscopic study of the temperature and distance dependence of the solvent reorganization energy in electron transfer reactions [D] . Vath, Peter A. 2000

机译：第一部分：皮秒光学量热法：分离焓和体积贡献，并从混合物研究确定绝对焓。第二部分电子转移反应中溶剂重组能的温度和距离依赖性的光谱研究
6. Enthalpies of mixing of liquid systems for lead free soldering:Al–Cu–Sn system [O] . Hans Flandorfer, Meryem Rechchach, A. Elmahfoudi, -1

机译：用于无铅焊接的液体系统混合焓：Al–Cu–Sn系统
7. Measurement and Prediction of Thermo Physical Properties to Study Intermolecular Interactions of Binary Liquid Mixtures at Various Temperatures by Using McAllister Modelud ud [O] . R. Ramesh, K. Ramesh, K. Yusoh 2014

机译：使用McAllister模型测量和预测热物理性质以研究二元液体混合物在不同温度下的分子间相互作用 ud
8. Enthalpy Charts: For Dissociating Gas Mixtures in the Temperature Range 600 deg to 4000 deg K [R] . H. REICHERT 1957

机译：焓图：用于在600度至4000度K的温度范围内离解气体混合物

Enthalpies of Mixing and Intermolecular Interactions in N,N-Dimethylformamide-Chloroform Systems at Temperatures Ranging between 288 and 308 K

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