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Nonlinear optical and optical power limiting studies on a new thiophene-based conjugated polymer in solution and solid PMMA matrix

机译:新型噻吩基共轭聚合物在溶液和固体PMMA基质中的非线性光学和光功率限制研究

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An experimental investigation of the third-order nonlinear optical properties of new poly(2-(5-[3,4-ditetradecyloxy-5-(1,3,4-oxadiazol-2-yl)thiophen-2-yl]-1,3,4-oxadiazol-2-yl}pyridine}(P)in tetrahydrofur-an (THF) solution and in solid poly( methylmethacrylate) (PMMA) matrix, by Z-scan technique isreported. The Z-scan traces reveal that the composite films exhibit large negative nonlinear refractiveindex of the order 10~(-10)esu. The excited-state absorption cross-section was found to be larger than theground-state absorption indicating that the operating nonlinear process is reverse saturable absorption(RSA). The new polymer P exhibits good optical power limiting properties in the nanosecond regime insolution and as well in solid PMMA matrix.
机译:新型聚(2-(5- [3- [3,4-二十四烷基氧基-5-(1,3,4-恶二唑-2-基)噻吩-2-基] -1]的三阶非线性光学性质的实验研究通过Z-扫描技术报道了在三氢呋喃(THF)溶液和固态聚(甲基丙烯酸甲酯)(PMMA)基质中的3,4-恶二唑-2-基}吡啶}(P),Z扫描痕迹表明:复合膜表现出较大的负非线性折射率,约为10〜(-10)esu,激发态吸收截面大于基态吸收截面,表明工作非线性过程为反饱和吸收(RSA)新型聚合物P在纳秒级溶液中以及在固态PMMA基质中均显示出良好的光功率限制性能。

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