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Observation of pure rotational absorption spectra in the upsilon(2) band of hot H2O in flames

机译:火焰中H2O的upsilon(2)谱带中的纯旋转吸收​​光谱的观察

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摘要

We present measurements of absorption spectra of hot-water vapor generated in a propane-air flame in the far-infrared region of the spectrum from 0.1 to 3.5 THz (3.3 to 117 cm(-1)). Transitions within the rotational manifold of both the ground and the nu(2) = 1 vibrational levels were observed. The measurements are in good agreement with calculations of the predicted absorption spectra at 1300 K based on tabulated line intensities, whereas predicted theoretical line widths were found to be approximately one third too narrow. (C) 1998 Optical Society of America. [References: 17]
机译:我们提出了在丙烷空气火焰中在0.1到3.5 THz(3.3到117 cm(-1))的远红外区域中产生的热水蒸气的吸收光谱的测量值。观察到地面和nu(2)= 1振动水平的旋转歧管内的过渡。这些测量值与基于列表线强度在1300 K时的预测吸收光谱的计算非常吻合,而预测的理论线宽大约太窄了三分之一。 (C)1998年美国眼镜学会。 [参考:17]

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