A copper- and amine-free Sonogashira reaction of aryl halides catalyzed by 1,3,5-triaza-7-phosphaadamantane palladium systems

Ruiz J; Cutillas N; Lopez F; Lopez G; Bautista D

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A copper- and amine-free Sonogashira reaction of aryl halides catalyzed by 1,3,5-triaza-7-phosphaadamantane palladium systems

机译：1,3,5-三氮杂-7-磷金刚烷钯体系催化的芳基卤化物的无铜和无胺Sonogashira反应

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The monomeric complex [Pd(dmba) Cl(PTA)] [dmba = N,C-chelating 2-(dimethylaminomethyl) phenyl; PTA = 1,3,5-triaza-7-phosphaadamantane] has been obtained and its crystal structure has been established by X-ray diffraction. Conditions for an efficient copper-and amine-free catalyzed Sonogashira reaction of aryl bromides and chlorides with terminal alkynes by [Pd(dmba)Cl(PTA)] and Pd(OAc)(2)/PTA have been developed. It is worthwhile noting that a relatively low palladium catalyst loading has been employed.

机译：单体配合物[Pd（dmba）Cl（PTA）] [dmba = N，C-螯合的2-（二甲基氨基甲基）苯基;获得了PTA ＝ 1,3,5-三氮杂-7-磷酸金刚烷]，并通过X射线衍射确定了其晶体结构。已经开发了通过[Pd（dmba）Cl（PTA）]和Pd（OAc）（2）/ PTA有效地催化芳基溴化物和氯化物与末端炔烃进行无铜和无胺催化的Sonogashira反应的条件。值得注意的是，已经使用了相对较低的钯催化剂负载量。

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《Organometallics》 |2006年第24期|共6页
作者
Ruiz J; Cutillas N; Lopez F; Lopez G; Bautista D;
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正文语种 eng
中图分类有机化学;
关键词
CROSS-COUPLING REACTIONS; OXIME-DERIVED PALLADACYCLES; TERMINAL ALKYNES; CRYSTAL-STRUCTURES; ROOM-TEMPERATURE; SHAPE-PERSISTENT; COORDINATION CHEMISTRY; COMPLEXES; BROMIDES; MACROCYCLES;

机译：交叉偶联反应;氧衍生的钯环;末端链烯;晶体结构;室温;形状持久性;配位化学;络合物;溴化物;宏指令;

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1. A copper- and amine-free Sonogashira reaction of aryl halides catalyzed by 1,3,5-triaza-7-phosphaadamantane palladium systems [J] . Ruiz J, Cutillas N, Lopez F, Organometallics . 2006,第24期

机译：1,3,5-三氮杂-7-磷金刚烷钯体系催化的芳基卤化物的无铜和无胺Sonogashira反应
2. Copper- and solvent-free Sonogashira coupling reactions of aryl halides with terminal alkynes catalyzed by 1-phenyl-1,2-propanedione-2-oxime thiosemi-carbazone-functionalized polystyrene resin supported Pd(II) complex under aerobic conditions [J] . Mohammad Bakherad, Ali Keivanloo, Bahram Bahramian Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2010,第1a2期

机译：1-苯基-1,2-丙二酮-2-肟硫代氨基甲酸官能化的聚苯乙烯树脂负载的Pd（II）络合物在有氧条件下催化芳基卤化物与末端炔烃的无铜和无溶剂Sonogashira偶联反应
3. An efficient protocol for copper- and amine-free Sonogashira reactions catalyzed by mononuclear palladacycle complexes containing bidentate phosphine ligands [J] . Seyyed Javad Sabounchei, Mohsen Ahmadi Catalysis Communications . 2013,第Null期

机译：含有双齿膦配体的单核新戊四环配合物催化的无铜和无胺Sonogashira反应的有效方案
4. Palladium-Catalyzed sila-Sonogashira Coupling Reactions of Alkynylsilanes with Aryl Chlorides [C] . Yasushi Nishihara, Eiji Inoue, Yoshiaki Okada Symposium on Organometallic Chemistry . 2008

机译：钯催化的Silka-sonogashira偶联反应炔基硅烷与芳基氯化物
5. Mechanism of the palladium-catalyzed amination of aryl halides: Kinetic studies of the oxidative addition of aryl halides and sulfonates to phosphine complexes of Pd(0) and of the catalytic reaction of amines with aryl halides and base. [D] . Alcazar-Roman, Luis Manuel. 2001

机译：钯催化芳基卤化物胺化的机理：动力学研究氧化芳基卤化物和磺酸盐到Pd（0）的膦配合物中，以及胺与芳基卤化物和碱的催化反应。
6. Sonogashira Reaction of Aryl and Heteroaryl Halides with Terminal Alkynes Catalyzed by a Highly Efficient and Recyclable Nanosized MCM-41 Anchored Palladium Bipyridyl Complex [O] . Bo-Nan Lin, Shao-Hsien Huang, Wei-Yi Wu, 2010

机译：高效和可回收的纳米级MCM-41钯钯联吡啶配合物催化芳基和杂芳基卤化物与末端炔烃的Sonogashira反应
7. Easy Copper-, Ligand- and Amine-Free Sonogashira Coupling Reaction Catalyzed by Palladium on Carbon at Low Catalyst Loading and by Exposure to Air [O] . G. Zhang 2005

机译：在低催化剂负载下钯催化钯碳含量易铜，配体和无胺的Sonogashira偶联反应，并通过暴露在空气中

A copper- and amine-free Sonogashira reaction of aryl halides catalyzed by 1,3,5-triaza-7-phosphaadamantane palladium systems

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