Iterative synthesis of oligoynes capped by a Ru-2(ap)(4)-terminus and their electrochemical and optoelectronic properties

Xu GL; Wang CY; Ni YH; Goodson TG; Ren T

首页> 外文期刊>Organometallics >Iterative synthesis of oligoynes capped by a Ru-2(ap)(4)-terminus and their electrochemical and optoelectronic properties

【24h】

Iterative synthesis of oligoynes capped by a Ru-2(ap)(4)-terminus and their electrochemical and optoelectronic properties

机译：Ru-2（ap）（4）-端基封端的低聚炔的迭代合成及其电化学和光电性能

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Cross-coupling reactions between terminal ethynes (HC-CY) and Ru-2(ap)(4)(C2(k-1)H) under Hay conditions, where ap is 2-anilinopyridinate and k = 2-5, resulted in compounds Ru2-(ap)(4)(C2kY) (Y = (SiPr3)-Pr-i and Ph) along with the homocoupling products YC4Y and [Ru-2(ap)(4)](2)-(mu-C4(k-1)). Compounds Ru-2(ap)(4)(C2kY) display two reversible RU2-based one-electron couples: an oxidation and a reduction. The HOMO-LUMO gaps (E-g) estimated from electrode potentials correlate linearly with the number of acetylenic bonds (k) within each series. Both nonlinear absorption and degenerate four-wave mixing measurements were carried out at both 532 and 800 nm with nano- and femtosecond laser pulses.

机译：末端乙炔（HC-CY）与Ru-2（ap）（4）（C2（k-1）H）在Hay条件下的交叉偶联反应，其中ap为2-苯胺基吡啶并k = 2-5化合物Ru2-（ap）（4）（C2kY）（Y =（SiPr3）-Pr-i和Ph）以及均耦合产物YC4Y和[Ru-2（ap）（4）]（2）-（mu- C4（k-1））。化合物Ru-2（ap）（4）（C2kY）显示出两个基于RU2的可逆单电子对：氧化和还原。根据电极电位估算的HOMO-LUMO间隙（E-g）与每个系列中的炔键（k）数量线性相关。使用纳秒和飞秒激光脉冲在532和800 nm处进行了非线性吸收和简并四波混频测量。

著录项

来源
《Organometallics》 |2005年第13期|共8页
作者
Xu GL; Wang CY; Ni YH; Goodson TG; Ren T;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
SP-CARBON CHAINS; NONLINEAR-OPTICAL PROPERTIES; TRANSITION-METAL-COMPLEXES; AMMINE ELECTRON-DONOR; PHOTOELECTRON-SPECTROSCOPY; ORGANOMETALLIC COMPLEXES; DIRUTHENIUM COMPOUNDS; MOLECULAR-STRUCTURES; COORDINATED CARBON; PI INTERACTIONS;

机译：SP碳链;非线性光学特性;过渡金属络合物;氨电子给体;光电子能谱;有机络合物;氘化合物;分子结构;碳原子;PI相互作用;

相似文献

外文文献
中文文献
专利

1. Iterative synthesis of oligoynes capped by a Ru-2(ap)(4)-terminus and their electrochemical and optoelectronic properties [J] . Xu GL, Wang CY, Ni YH, Organometallics . 2005,第13期

机译：Ru-2（ap）（4）-端基封端的低聚炔的迭代合成及其电化学和光电性能
2. Synthesis and characterization of (3,1) Ru-2(F(3)aP)(4)(NCS) and (3,1) Ru-2(F(3)ap)(3)(F(2)Oap)(NCS) where F(3)ap is the 2-(2,4,6-trifluoroanilino)pyridinate anion [J] . Nguyen M, Phan T, Van Caemelbecke E, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2008,第10期

机译：（3,1）Ru-2（F（3）aP）（4）（NCS）和（3,1）Ru-2（F（3）ap）（3）（F（2）Oap ）（NCS）其中F（3）ap是2-（2,4,6-三氟苯胺基）吡啶酸根阴离子
3. ISOMER EFFECT ON THE STRUCTURE AND CHEMICAL REACTIVITY OF DIRUTHENIUM COMPLEXES - SYNTHESIS AND CHARACTERIZATION OF THE (4,0), (3,1), AND (2,2) TRANS ISOMERS OF RU-2(F(5)AP)(4)CL AND RU-2(F(5)AP)(4)(C-EQUIVALENT-TO-CC6H5)(2) WHERE F(5)AP IS THE 2-(2, [J] . Bear JL., Han BC., Vancaemelbecke E., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1997,第24期

机译：异构体对二钌络合物的结构和化学反应性的影响-RU-2（F（5）AP）（4）的（4,0），（3,1）和（2,2）反式异构体的合成与表征）CL和RU-2（F（5）AP）（4）（C-等效于CC6H5）（2），而F（5）AP为2-（2，
4. Synthesis and electrochemical properties of nanorod polyaniline/activated carbon composites for electrochemical capacitor [C] . Lan Liu, Wei Wang, Benlin He, International conference on multi-functional materials and structures . 2009

机译：电化学电容器用纳米棒聚苯胺/活性炭复合材料的合成及电化学性能
5. Synthesis snd Study of the Electrochemical and Optoelectronic Properties of pi-Conjugated Poly-P-Phenylene-Based Molecular Wires. [D] . Boddeda, Anitha. 2017

机译：π共轭基于聚对-P-苯的分子线的电化学和光电性能的合成及研究。
6. Structural Properties of the C Terminus of Vesicular Stomatitis Virus N Protein Dictate N-RNA Complex Assembly Encapsidation and RNA Synthesis [O] . Bianca S. Heinrich, Benjamin Morin, Amal A. Rahmeh, 2012

机译：水泡性口腔炎病毒N蛋白听写C总站的结构特性NRNA复杂衣壳化和RNA合成。
7. Iterative Synthesis of Oligoynes Capped by a Ru2(ap)4-terminus and Their Electrochemical and Optoelectronic Properties [O] . -1

机译：用Ru2（AP）4-末端的Oligoynes合成及其电化学和光电性能

Iterative synthesis of oligoynes capped by a Ru-2(ap)(4)-terminus and their electrochemical and optoelectronic properties

摘要

著录项

相似文献

相关主题

期刊订阅