Hydrovinylation of Alkenes Catalyzed by the Ruthenium-Hydride Complex Formed in Situ from (PCy_3)_2(CO)RuHCl and HBF_4 centre dot OEt_2

Chae S. Yi; Zhengjie He; Do W. Lee

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Hydrovinylation of Alkenes Catalyzed by the Ruthenium-Hydride Complex Formed in Situ from (PCy_3)_2(CO)RuHCl and HBF_4 centre dot OEt_2

机译：由（PCy_3）_2（CO）RuHCl和HBF_4中心点OEt_2原位形成的钌-氢化物配合物催化烯烃的氢乙烯基化

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摘要

A ruthenium-hydride complex, generated in situ form the reaction of (PCy_3)_2(CO)RuHCl (1) with HBF centre dot OEt_2, was found to be an effective catalyst for the hydrovinylation of alkenes.

机译：发现通过（PCy_3）_2（CO）RuHCl（1）与HBF中心点OEt_2反应原位生成的氢化钌络合物是烯烃加氢乙烯基化的有效催化剂。

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《Organometallics》 |2001年第4期|共9页
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Chae S. Yi; Zhengjie He; Do W. Lee;
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正文语种 eng
中图分类有机化学;有机质材料;
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1. Hydrovinylation of Alkenes Catalyzed by the Ruthenium-Hydride Complex Formed in Situ from (PCy_3)_2(CO)RuHCl and HBF_4 centre dot OEt_2 [J] . Chae S. Yi, Zhengjie He, Do W. Lee Organometallics . 2001,第4期

机译：由（PCy_3）_2（CO）RuHCl和HBF_4中心点OEt_2原位形成的钌-氢化物配合物催化烯烃的氢乙烯基化
2. Intermolecular coupling reaction of cyclic amines and alkenes catalyzed by a ruthenium-hydride complex (PCy3)(2)(CO)RuHCl [J] . Yi CS, Yun SY, Guzei IA Organometallics . 2004,第23期

机译：氢化钌络合物（PCy3）（2）（CO）RuHCl催化的环胺与烯烃的分子间偶联反应
3. Acid-promoted homogeneous hydrogenation of alkenes catalyzed by the ruthenium-hydride complex (PCy3)(2)(CO)(Cl)RuH: Evidence for the formation of 14-electron species from the selective entrapment of the phosphine ligand [J] . Yi CS., He ZJ., Rheingold AL., Organometallics . 2000,第15期

机译：氢化钌络合物（PCy3）（2）（CO）（Cl）RuH催化的酸促进烯烃的均相加氢：膦配体的选择性包埋形成14电子物种的证据
4. Hydroaminoalkylation of Alkenes Catalyzed by AlkyltitaniumComplexes [C] . Mariko Inoue, Mai Mizukami, Hayato Tsurugi 日本化学会春季年会 . 2020

机译：通过烷基钛合式用催化的烯烃的氨基烷基化
5. Transition Metal Catalyzed Enantioselective Hydroboration and Hydrovinylation of Alkenes [D] . Duvvuri, Krishnaja 2018

机译：过渡金属催化烯烃的对映选择性硼氢化和氢乙烯基化
6. Regioselective Intermolecular Coupling Reaction of Arylketones and Alkenes Involving C-H Bond Activation Catalyzed by an In-Situ Formed Cationic Ruthenium-Hydride Complex [O] . Chae S. Yi, Do W. Lee -1

机译：arylketones和烯烃通过原位形成的阳离子钌氢化物络合物涉及C-H键活化催化的区域选择性分子间偶联反应
7. Intermolecular Coupling Reaction of Cyclic Amines and Alkenes Catalyzed by a Ruthenium-Hydride Complex (PCy3)2(CO)RuHCl [O] . -1

机译：氢化钌 - 氢化物络合物（PCY3）2（CO）RuHCL催化的循环胺和烯烃的分子间偶联反应

Hydrovinylation of Alkenes Catalyzed by the Ruthenium-Hydride Complex Formed in Situ from (PCy_3)_2(CO)RuHCl and HBF_4 centre dot OEt_2

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