Novel iridium complexes containing 2,6-bis(oxazoline)pyridine ligands: Synthesis and reactivity of the diolefin iridium(I) complex [Ir(eta(2)-C2H4)(2){kappa N-3,N,N-(S,S)-i-Pr-pybox}][PF6] ((S,S)-i-Pr-pybox=2,6-Bis(4 '-(S)-isopropyloxazolin-2 '-yl)py

Diez J; Gamasa MP; Gimeno J; Paredes P

首页> 外文期刊>Organometallics >Novel iridium complexes containing 2,6-bis(oxazoline)pyridine ligands: Synthesis and reactivity of the diolefin iridium(I) complex [Ir(eta(2)-C2H4)(2){kappa N-3,N,N-(S,S)-i-Pr-pybox}][PF6] ((S,S)-i-Pr-pybox=2,6-Bis(4 '-(S)-isopropyloxazolin-2 '-yl)py

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Novel iridium complexes containing 2,6-bis(oxazoline)pyridine ligands: Synthesis and reactivity of the diolefin iridium(I) complex [Ir(eta(2)-C2H4)(2){kappa N-3,N,N-(S,S)-i-Pr-pybox}][PF6] ((S,S)-i-Pr-pybox=2,6-Bis(4 '-(S)-isopropyloxazolin-2 '-yl)py

机译：新型的含2,6-双（恶唑啉）吡啶配体的铱配合物：二烯烃铱（I）配合物[Ir（eta（2）-C2H4）（2）{kappa N-3，N，N-（ S，S）-i-Pr-pybox}] [PF6]（（S，S）-i-Pr-pybox = 2,6-Bis（4'-（S）-异丙基恶唑啉-2'-yl）py

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The novel iridium(I)-pybox complexes [Ir(Ln)(n)-{kappa(3)N,N,N-(S,S)-i-Pr-pybox}][PF6] (n = 2, L = eta(2)-C2H4 (1), eta(2)-MeO2CC&3bond; CCO2Me (2); n = 1, L = CO (3)) have been synthesized. The treatment of complex 1 with HCl or allyl chloride under very mild conditions results in the stereoselective formation of the complexes [IrClH(eta(2)-C2H4){kappa(3)N,N,N-(S,S)-i-Pr-pybox}][PF6] (4) and [IrCl(eta(3)-C3H5){(KN)-N-3,N,N-(S,S)-i-Pr-pybox}][PF6] (5). The structures of complexes 1 and 5 have been determined by X-ray diffraction analyses.

机译：新型铱（I）-pybox络合物[Ir（Ln）（n）-{kappa（3）N，N，N-（S，S）-i-Pr-pybox}] [PF6]（n = 2， L = eta（2）-C2H4（1），eta（2）-MeO2CC＆3bond; CCO2Me（2）; n = 1，L = CO（3））已合成。在非常温和的条件下用HCl或烯丙基氯处理复合物1导致立体选择性形成复合物[IrClH（eta（2）-C2H4）{kappa（3）N，N，N-（S，S）-i -Pr-pybox}] [PF6]（4）和[IrCl（eta（3）-C3H5）{（KN）-N-3，N，N-（S，S）-i-Pr-pybox}]] [ PF6]（5）。配合物1和5的结构已经通过X射线衍射分析确定。

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《Organometallics》 |2005年第8期|共4页
作者
Diez J; Gamasa MP; Gimeno J; Paredes P;
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正文语种 eng
中图分类有机化学;
关键词
ALLYLIC SUBSTITUTION; IR-III; CATALYSTS; OLEFINS; PYBOX; BEHAVIOR; KETONES;

机译：烯丙基取代;IR-III;催化剂;烯烃;PYBOX;行为;酮;

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1. Novel iridium complexes containing 2,6-bis(oxazoline)pyridine ligands: Synthesis and reactivity of the diolefin iridium(I) complex [Ir(eta(2)-C2H4)(2){kappa N-3,N,N-(S,S)-i-Pr-pybox}][PF6] ((S,S)-i-Pr-pybox=2,6-Bis(4 '-(S)-isopropyloxazolin-2 '-yl)py [J] . Diez J, Gamasa MP, Gimeno J, Organometallics . 2005,第8期

机译：新型的含2,6-双（恶唑啉）吡啶配体的铱配合物：二烯烃铱（I）配合物[Ir（eta（2）-C2H4）（2）{kappa N-3，N，N-（ S，S）-i-Pr-pybox}] [PF6]（（S，S）-i-Pr-pybox = 2,6-Bis（4'-（S）-异丙基恶唑啉-2'-yl）py
2. Efficient orange-red electroluminescence of iridium complexes with 1-(2,6-bis(trifluoromethyl) pyridin-4-yl) isoquinoline and 4-(2,6-bis (trifluoromethyl) pyridin-4-yl) quinazoline ligands [J] . Han Hua-Bo, Cui Rong-Zhen, Lu Guang-Zhao, Dalton transactions: An international journal of inorganic chemistry . 2017,第43期

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3. One-pot stereoselective synthesis of organorhodium(III) complexes containing the chiral ligand 2,6-bis[4'-(S)-isopropyloxazolin-2'-yl]pyridine (Pr-i-pybox) [J] . Cuervo D, Diez J, Gamasa MP, Organometallics . 2005,第9期

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4. Substituent Effect in Spin-Crossover Behavior of Iron(II)-Ar-pybox Complexes (Ar-pybox= 4-Aryl-2,6-bis(oxazolin-2-yl)pyridine) [C] . Akifumi Kimura, Takayuki Ishida Irago Conference . 2018

机译：铁（II）-AR-ubox络合物的旋转交叉行为中的取代基效应（Ar-pybox = 4-芳基-2,6-双（恶唑啉-2-基）吡啶）
5. I. Synthesis, reactivity, and structural studies of rhodium(III) and rhodium(II) complexes of novel bis(oxazoline) pincer ligands. II. Synthesis and reactivity of novel rhenium methylidene complexes. [D] . Krumper, Jennifer. 2003

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6. Studies on Some New Ru(III) Complexes Using aryl-azo Pentane-2,4-dione and 2,6-bis (2'-Benzimidazolyl) Pyridine as Ligands:Synthesis, Spectroscopic, Luminescent, Electrochemical and Biological Activities [O] . Lallan Mishra, Ajay K. Yadaw, Ratna S. Phadke, 1947

机译：用芳基偶氮戊烷-研究一些新的Ru（III）配合物2,4-二酮和2,6-双（2'-苯并咪唑基）吡啶为配体：合成，光谱，发光，电化学和生物活性
7. Novel Iridium Complexes Containing 2, 6-Bis(oxazoline)pyridine Ligands: Synthesis and Reactivity of the Diolefin Iridium(I) Complex Ir(h2-C2H4)2{k3N, N, N-(S, S)-i-Pr- pybox}PF6 ((S, S)-i-Pr-pybox = 2, 6-Bis(4-(S)-isopropyloxazolin-2-yl) pyridine) [O] . -1

机译：含有2,6-双（恶唑啉）吡啶配体的新型铱络合物：二烯烃铱（I）复合物的合成和反应性IR（H2-C2H4）2 {K3N，N，N-（S，S）-I-PR - pybox} PF6（（s，s）-i-pr-pybox = 2,6-双（4-（s） - 异丙恶唑啉-2-基）吡啶）

Novel iridium complexes containing 2,6-bis(oxazoline)pyridine ligands: Synthesis and reactivity of the diolefin iridium(I) complex [Ir(eta(2)-C2H4)(2){kappa N-3,N,N-(S,S)-i-Pr-pybox}][PF6] ((S,S)-i-Pr-pybox=2,6-Bis(4 '-(S)-isopropyloxazolin-2 '-yl)py

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