Bifunctional imidazolylphosphine ligands as hydrogen bond donors promote N-H and O-H activation on platinum

Grotjahn DB; Gong Y; DiPasquale AG; Zakharov LN; Rheingold AL

首页> 外文期刊>Organometallics >Bifunctional imidazolylphosphine ligands as hydrogen bond donors promote N-H and O-H activation on platinum

【24h】

Bifunctional imidazolylphosphine ligands as hydrogen bond donors promote N-H and O-H activation on platinum

机译：双官能咪唑基膦配体作为氢键供体可促进铂上的N-H和O-H活化

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The NH moieties of two imidazolylphosphine ligands on Pt(II) facilitate formation of trans-(hydrido)((RO)-O-1) bis-(phosphine) Pt(II) species from (ROH)-O-1 (R-1 = CF3CO, CH3CO, Ph, CH3, H). Evidence points to formation of a reliable binding pocket for coordinated (RO)-O-1 by hydrogen bond donation from the two NH groups.

机译：Pt（II）上两个咪唑基膦配体的NH部分有助于由（ROH）-O-1（R-）形成反式（氢）（（RO）-O-1）双-（膦）Pt（II）物种1 = CF3CO，CH3CO，Ph，CH3，H）。有证据表明，通过两个NH基团的氢键捐赠形成了可靠的配位基，用于配位（RO）-O-1。

著录项

来源
《Organometallics》 |2006年第24期|共3页
作者
Grotjahn DB; Gong Y; DiPasquale AG; Zakharov LN; Rheingold AL;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
OXIDATIVE-ADDITION-REACTIONS; ANTI-MARKOVNIKOV HYDRATION; IR-I COMPLEXES; C-H; REDUCTIVE ELIMINATION; HOMOGENEOUS CATALYSIS; PALLADIUM COMPLEXES; HYDRIDE COMPLEXES; TERMINAL ALKYNES; WATER;

机译：氧化-加成反应;抗-马尔可夫尼科夫水合;IR-I络合物;C-H;还原消除;均相催化;钯络合物;氢化物络合物;末端烷基;水;

相似文献

外文文献
中文文献
专利

1. Bifunctional imidazolylphosphine ligands as hydrogen bond donors promote N-H and O-H activation on platinum [J] . Grotjahn DB, Gong Y, DiPasquale AG, Organometallics . 2006,第24期

机译：双官能咪唑基膦配体作为氢键供体可促进铂上的N-H和O-H活化
2. N-H and C-H Bond Activations of an Isoindoline Promoted by Iridium- and Osmium-Polyhydride Complexes: A Noninnocent Bridge Ligand for Acceptorless and Base-Free Dehydrogenation of Secondary Alcohols [J] . Buil Maria L., Esteruelas Miguel A., Izquierdo Susana, Organometallics . 2020,第14期

机译：由铱和锇 - 多氢化物复合物促进的异吲哚啉的N-H和C-H键活化：仲醇的无生物体桥配体，用于仲醇的无碱性脱氢
3. Activation of C-H, N-H, and O-H Bonds via Proton-Coupled Electron Transfer to a Mn(Ⅲ) Complex of Redox-Noninnocent Octaazacyclotetradecadiene, a Catenated-Nitrogen Macrocyclic Ligand [J] . Vaddypally Shivaiah, Tomlinson Warren, OSullivan Owen T., Journal of the American Chemical Society . 2019,第14期

机译：通过质子耦合电子转移到氧化氮-非无色八氮杂环十四癸二烯（一种链状氮大环配体）的Mn（Ⅲ）配合物上来活化C-H，N-H和O-H键
4. Anharmonicity in the Vibrational Modes Associated with H-H, N-H, O-H, and C-H bonds [C] . Sukit Limpijumnong Symposium Proceedings vol.813; Symposium on Hydrogen in Semiconductors; 20040413-14; San Francisco,CA(US) . 2004

机译：与H-H，N-H，O-H和C-H键相关的振动模式下的非谐性
5. Synthesis and reactivity of ruthenium and platinum complexes with non-dative heteroatomic ligands: Studies of carbon -hydrogen bond activation [D] . Feng, Yuee 2008

机译：具有非衍生杂原子配体的钌和铂配合物的合成和反应性：碳氢键活化的研究
6. Rhodium and Iridium Mediated C-H and O-H Bond Activation of Two Schiff Base Ligands: Synthesis Characterization and Catalytic Properties of the Organometallic Complexes [O] . Poulami Sengupta, Rituparna Das, Papu Dhibar, 2021

机译：铑和铱介导的C-H和O-H键活化两种席夫碱配体：有机金属配合物的合成表征和催化性能
7. Bifunctional Imidazolylphosphine Ligands as Hydrogen Bond Donors Promote N-H and O-H Activation on Platinum [O] . -1

机译：双官能咪唑基膦配体作为氢键供体促进铂的N-H和O-H活化
8. Moving to Sustainable Metals. Multi-Functional Ligands In Catalytic, Outer Sphere C-h, N-h and O-h Activation. [R] . Crabtree, R. 2015

机译：转向可持续金属。催化，外球C-h，N-h和O-h活化中的多功能配体。

Bifunctional imidazolylphosphine ligands as hydrogen bond donors promote N-H and O-H activation on platinum

摘要

著录项

相似文献

相关主题

期刊订阅