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Synthesis and characterization of yttrium complexes containing a tridentate linked amido-cyclopentadienyl ligand

机译:含三齿连接的酰胺基-环戊二烯基配体的钇配合物的合成与表征

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摘要

The reaction of dilithium salts of the tridentate linked amido-cyclopentadienyl ligands Li-2(C5Me4SiMe2NCH2CH2X) (X = OMe, NMe2, CH2OMe) with [Y(o-C6H4CH2NMe2)Cl-2(LiCl)(THF)(4)] and Y(eta(5)-C5H5)Cl-2(THF)(3) give chloro-bridged ate complexes of the type [Li(THF)][Y(eta(5):eta(1)-C5Me4SiMe2NCH2CH2X) (R)Cl], where R = o-C6H4CH2NMe2, eta(5)-C5H5. [References: 38]
机译:三齿连接的酰胺基-环戊二烯基配体Li-2(C5Me4SiMe2NCH2CH2X)(X = OMe,NMe2,CH2OMe)的二锂盐与[Y(o-C6H4CH2NMe2)Cl-2(LiCl)(THF)(4)]和Y(eta(5)-C5H5)Cl-2(THF)(3)得到[Li(THF)] [Y(eta(5):eta(1)-C5Me4SiMe2NCH2CH2X)(R )Cl],其中R = o-C6H4CH2NMe2,eta(5)-C5H5。 [参考:38]

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