A 'Push-Pull' Phosphasilene and Phosphagermene and Their Anion-Radicals

Lee Vladimir Ya; Kawai Manami; Sekiguchi Akira; Ranaivonjatovo Henri; Escudie Jean

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A 'Push-Pull' Phosphasilene and Phosphagermene and Their Anion-Radicals

机译：“推挽式”磷腈和磷锗烯及其阴离子基团

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Phosphasilene 1a and phosphagermene 1b, featuring unprecendented substitution patterns (donors on Si or Ge and acceptor on P), were synthesized utilizing a one-step synthetic approach; direct coupling of dilithiosilane/dilithiogermane and dichlorophosphine. The structural features of both 1a and 1b based on their NMR and X-ray crystal data are discussed, as well as their one-electron reduction forming persistent phosphasilene and phosphagermene anion-radicals.

机译：采用一步合成的方法合成了具有无与伦比的取代模式（Si或Ge上的施主和P上的受主）的磷腈1a和磷腈1b。二硫代硅烷/二硫代锗烷与二氯膦的直接偶联。根据1a和1b的NMR和X射线晶体数据，讨论了1a和1b的结构特征，以及它们的单电子还原反应，形成了持久的磷腈和磷代戊二烯根基。

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来源
《Organometallics》 |2009年第15期|共4页
作者
Lee Vladimir Ya; Kawai Manami; Sekiguchi Akira; Ranaivonjatovo Henri; Escudie Jean;
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正文语种 eng
中图分类 545B0014-1;
关键词
PHOSPHORUS DOUBLE-BOND; ARSENIC DOUBLE-BONDS; X-RAY-STRUCTURE; SILYLIDENE-PHOSPHANES; SILICON-PHOSPHORUS; STABLE COMPOUND; REACTIVITY; DIPHOSPHENE; GENERATION; DISILENES;

机译：磷双键;砷双键;X射线结构;甲硅烷基磷;硅磷;稳定的化合物;反应性;二膦;生成;二甲苯;

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1. A "Push-Pull" Phosphasilene and Phosphagermene and Their Anion-Radicals [J] . Lee Vladimir Ya, Kawai Manami, Sekiguchi Akira, Organometallics . 2009,第15期

机译：“推挽式”磷腈和磷锗烯及其阴离子基团
2. Oxidation of hydro-silaimine, phosphasilene, and arsasilene structures (CH 3)HSiE(CH 3) (E: N, P, or As) via concerted 1,3-dipolar cycloaddition of nitrous oxide: A DFT study [J] . Cem Burak Yildiz Computational & theoretical chemistry . 2018,第期

机译：氢 - 硅松，磷钛和胂和胂结构的氧化（CH 3 ）HSIE（CH 3 ）（E：N，P，或AS）通过齐节的1,3-偶极环加成二氮氧化物：DFT研究
3. Diverse Reactivity of an Electrophilic Phosphasilene towards Anionic Nucleophiles: Substitution or Metal-Amino Exchange [J] . Willmes Philipp, Junk Lukas, Huch Volker, Angewandte Chemie . 2016,第36期

机译：亲电性Phosphasilene对阴离子亲核试剂的不同反应性：取代或金属氨基交换。
4. Synthesis and Characterization of Phosphasilenes Stabilized by Bulky Rind Groups [C] . Baolin Li, Daisuke Hashizume, Tsukasa Matsuo Symposium on Organometallic Chemistry . 2008

机译：庞大RIND基团稳定的磷酸化的合成与表征
5. Designing robust supply chains using a new hybrid push-pull control with multiple push-pull boundaries. [D] . Kim, SeungHwan. 2008

机译：使用具有多个推挽边界的新型混合推挽控制设计坚固的供应链。
6. Copper-catalyzed oxidative benzylic C-H cyclization via iminyl radical from intermolecular anion-radical redox relay [O] . Xiang-Huan Shan, Hong-Xing Zheng, Bo Yang, -1

机译：铜催化的分子间阴离子-自由基氧化还原中继反应中亚胺基的氧化苄基C-H环化反应
7. Free Radical Chemistry of Phosphasilenes [O] . Kerim Samedov, Yannic Heider, Yuanjing Cai, 2020

机译：磷酸化的自由基化学
8. Bent Cyclopolysilane Anion-Radical (i-Pr2Si)4 [R] . Wadsworth, C. L., West, R., Nagai, Y., 1985

机译：弯曲的Cyclopolysilane阴离子 - 自由基（i-pr2si）4

A 'Push-Pull' Phosphasilene and Phosphagermene and Their Anion-Radicals

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