An estimate of the reduction potential of B(C6F5)(3) from electrochemical measurements on related mesityl boranes

Cummings SA; Iimura M; Harlan CJ; Kwaan RJ; Trieu IV; Norton JR; Bridgewater BM; Jakle F; Sundararaman A; Tilset M

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An estimate of the reduction potential of B(C6F5)(3) from electrochemical measurements on related mesityl boranes

机译：通过对相关均三甲硼烷的电化学测量估算B（C6F5）（3）的还原电位

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MesB(C6F5)(2) (1) has been prepared from MesMgBr and FB(C6F5)(2)(OEt2)-O-., while Mes(2)B(C6F5) (2) is readily available from CuC6F5 and Mes(2)BBr. The reduction potential E degrees of 1 vs Cp2Fe0/+ in THF is - 1.72 V, while that of 2 is -2.10 V, and that Of Mes(3)B (3) is -2.73 V. B-11 and H-1 NMR show that neither I nor 2 binds THF significantly. These results have been used to estimate the reduction potential of B(C6F5)(3) in THF as -1.17 V vs Cp2Fe0/+ or as -0.64 V vs SCE.

机译：MesB（C6F5）（2）（1）已由MesMgBr和FB（C6F5）（2）（OEt2）-O-制备，而Mes（2）B（C6F5）（2）可从CuC6F5和Mes获得（2）溴化硼B-1和H-1在THF中1对Cp2Fe0 / +的还原电位E程度为-1.72 V，而2的还原电位为-2.10 V，而Mes（3）B（3）的还原电位为-2.73 V. NMR显示I或2均未显着结合THF。这些结果已用于估计B（C6F5）（3）在THF中的还原电位为-1.17 V对Cp2Fe0 / +或-0.64 V对SCE。

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《Organometallics》 |2006年第7期|共4页
作者
Cummings SA; Iimura M; Harlan CJ; Kwaan RJ; Trieu IV; Norton JR; Bridgewater BM; Jakle F; Sundararaman A; Tilset M;
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正文语种 eng
中图分类有机化学;
关键词
CATALYST SYSTEMS; ADDUCT FORMATION; COMPLEXES; TRIS(PENTAFLUOROPHENYL)BORANE; CRYSTAL; CHEMISTRY; LIGANDS; PATHWAY; BINDING; ACIDITY;

机译：催化剂体系;加合物的形成;络合物;三（五氟联苯）硼烷;晶体;化学;液体;通路;键合;酸度;

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An estimate of the reduction potential of B(C6F5)(3) from electrochemical measurements on related mesityl boranes

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