Synthesis and Structure of [Li2C(PPh2=NSiMe3)(PPh2=S)]: A Geminal Dianionic Ligand

Chen Jun-Hui; Guo Jiayi; Li Yongxin; So Cheuk-Wai

首页> 外文期刊>Organometallics >Synthesis and Structure of [Li2C(PPh2=NSiMe3)(PPh2=S)]: A Geminal Dianionic Ligand

【24h】

Synthesis and Structure of [Li2C(PPh2=NSiMe3)(PPh2=S)]: A Geminal Dianionic Ligand

机译：[Li2C（PPh2 = NSiMe3）（PPh2 = S）]的合成和结构：双键双阳离子配体

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The (iminophosphoranyl)(thiophosphoranyl)methane [CH2(PPh2 = NSiMe3)(PPh2 = S)] (2) was obtained by the reaction of the phosphine-phosphinimine [Ph2PCH2(PPh2 = NSi-Me-3)] (1) with sulfur in toluene. Treatment of 2 with Bu" Li in THF at - 90 degrees C afforded the lithium (iminophosphoranyl)(thiophosphoranyl)methanide [Li{CH(PPh2 = S)PPh2 = NSiMe3)}] (3) The geminal dianion derivative [Li-2{C(PPh2 = S)(PPh2 = NSiMe3)}] (4) was synthesized by double deprotonation of 2 with a stoichiometric amount of Bu' Li in Et2O at - 90 degrees C. The structures of compounds 2-4 have been determined by X-ray crystallography.

机译：通过亚膦膦胺[Ph2PCH2（PPh2 = NSi-Me-3）]（1）与（亚胺基膦酰基）（硫代膦烷基）甲烷[CH2（PPh2 = NSiMe3）（PPh2 = S）]（2）反应制得甲苯中的硫。在90°C下用THF中的Bu“ Li处理2，得到亚氨基锂（亚氨基磷杂烷基）（硫代磷杂烷基）甲烷[Li {CH（PPh2 = S）PPh2 = NSiMe3）}]（3）双晶双阴离子衍生物[Li-2 {C（PPh2 = S）（PPh2 = NSiMe3）}]（4）通过在90摄氏度下于Et2O中用化学计量的Bu'Li进行2的双质子化而合成。（4）已确定化合物2-4的结构通过X射线晶体学。

著录项

来源
《Organometallics》 |2009年第15期|共4页
作者
Chen Jun-Hui; Guo Jiayi; Li Yongxin; So Cheuk-Wai;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类 545B0014-1;
关键词
GROUP-10 METAL CENTERS; X-RAY-STRUCTURE; CARBENE COMPLEXES; COORDINATION CHEMISTRY; IMINOPHOSPHORANE; REACTIVITY; CHELATE; BIS(PHOSPHINIMINO)METHANIDES; DERIVATIVES; METHANIDE;

机译：第10组金属中心;X射线结构;碳络合物;配位化学;亚氨基RE;反应性;螯合物;双（次膦）甲醇;衍生物;

相似文献

外文文献
中文文献
专利

1. Synthesis and Structure of [Li2C(PPh2=NSiMe3)(PPh2=S)]: A Geminal Dianionic Ligand [J] . Chen Jun-Hui, Guo Jiayi, Li Yongxin, Organometallics . 2009,第15期

机译：[Li2C（PPh2 = NSiMe3）（PPh2 = S）]的合成和结构：双键双阳离子配体
2. Reactivity of a Tin(II) (Iminophosphinoyl)(thiophosphinoyl)methanediide Complex Toward Sulfur: Synthesis and 119Sn Mössbauer Spectroscopic Studies of [{(μ-S)SnC(PPh2═NSiMe3)(PPh2═S)}3Sn(μ3-S)] [J] . Jia-Yi Guo Hong-Wei Xi Israel Nowik Rolfe H. Herber Yongxin Li Kok Hwa Lim and Cheuk-Wai So Inorganic Chemistry . 2012,第7期

机译：锡（II）（亚氨基膦酰基）（硫代膦酰基）甲烷二酰亚胺配合物对硫的反应活性：[{（μ-S）SnC（PPh2═NSiMe3）（PPh2═S）} 3Sn（μ3-S）的合成和119SnMössbauer光谱研究]
3. SYNTHESES AND STRUCTURES OF [(THF)(N)M((NSIME3)(2)PPH2)2] COMPLEXES (M=BE, MG, CA, SR, BA N=0-2) - DEVIATION OF ALKALINE EARTH METAL CATIONS FROM THE PLANE OF AN ANIONIC LIGAND [J] . Fleischer R., Stalke D. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1997,第11期

机译：[（THF）（N）M（（NSIME3）（2）PPH2）2]配合物的合成与结构（M = BE，MG，CA，SR，BA N = 0-2）-碱土金属阳离子的偏离阴离子配体的平面
4. A General Route to M4N4 Heterocubanes: Synthesis and Crystal Structure of M(μ3 NSiMe3)4 (M=Ge, Pb) [C] . Jack F. Eichler, Oliver Just, William S. Rees Jr. American Chemical Society . 2006

机译：到M4N4杂铝的一般途径：M（μ3nsime3） 4（m = ge，pb）的合成和晶体结构
5. Synthesis and characterization of high energy-density N-nitramino, geminal dinitro and geminal difluoramino propellants. [D] . Qi, Lida. 2004

机译：高能量密度N-硝胺，双硝基二硝基和双氟氨基双推进剂的合成与表征。
6. Myxococcus xanthus Pph2 Is a Manganese-dependent Protein Phosphatase Involved in Energy Metabolism [O] . Raquel García-Hernández, Aurelio Moraleda-Muñoz, Alfredo Castañeda-García, 2009

机译：粘球菌黄单胞菌Pph2是涉及能量代谢的锰依赖性蛋白磷酸酶。
7. Synthesis of a labile sulfur-centred ligand, [S(H)C(PPh2S)2]-: structural diversity in lithium(i), zinc(ii) and nickel(ii) complexes [O] . Thirumoorthi, Ramalingam, Chivers, Tristram, Häggman, Susanna, 2016

机译：不稳定的以硫为中心的配体[S（H）C（PPh2S）2]-的合成：锂（i），锌（ii）和镍（ii）配合物中的结构多样性
8. Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 89. (1) Tetra- and Penta-nuclear Tungsten-Rhodium Complexes: Crystal Structures of (W3Rh2(mu-CO)2(mu-CMe)(mu-C(Me)C(O))(Mu-PPh2)2-(Mu3-CMe)(CO)2(eta- C5H5)3) and (W3Rh2(mu-CO)3(mu-CMe)(mu-C(Me)PPh2)(mu3-CMe)-(CO)2(mu-C5H5)3). [R] . Davies, S. J., Stone, F. G., Howard, J. A., 1989

机译：具有桥接卡宾或卡宾配体的多核金属配合物的化学。第89部分。（1）四核和五核钨铑配合物：（W3Rh2（mu-CO）2（mu-Cme）（μ-C（me）C（O））（mu-pph2）的晶体结构2-（mu3-Cme）（CO）2（eta-C5H5）3）和（W3Rh2（mu-CO）3（mu-Cme）（μ-C（me）pph2）（mu3-Cme） - （CO） 2（mU-C5H5）3）。

Synthesis and Structure of [Li2C(PPh2=NSiMe3)(PPh2=S)]: A Geminal Dianionic Ligand

摘要

著录项

相似文献

相关主题

期刊订阅