The First Structural Characterization of alpha-Zincated(Reformatsky)Amides and Phosphine Oxides

Mark L.Hlavinka; John R.Hagadorn

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The First Structural Characterization of alpha-Zincated(Reformatsky)Amides and Phosphine Oxides

机译：α-锌（Reformatsky）酰胺和氧化膦的第一个结构表征

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Reformatsky reagents comprise a class of alpha-function-alized organozincs that are widely used as C-nucleo-philes in synthetic organic chemistry.These mildly basic species tolerate most organic functionalities and therefore are well suited for uses involving complex functionalized molecules.There are several different types of Reformatsky reagents.The most extensively studied have been the Reformatsky esters,but related derivatives of amides,phosphonates,imines,and hy-drazones are increasingly being used.Reformatsky reagents readily undergo transmetalation reactions with transition-metal salts.Consequently,they are useful intermediates in a variety of Cu-and Pd-mediated coupling reactions.

机译：Reformatsky试剂包含一类被阿尔法功能化的有机锌，这些锌在合成有机化学中被广泛用作C-亲核试剂，这些温和的碱性物质可耐受大多数有机功能，因此非常适合涉及复杂功能化分子的用途。不同种类的Reformatsky试剂。最广泛研究的是Reformatsky酯，但越来越多地使用酰胺，膦酸酯，亚胺和hy的相关衍生物.Reformatsky试剂易于与过渡金属盐发生金属转移反应。在各种Cu和Pd介导的偶联反应中是有用的中间体。

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《Organometallics》 |2005年第17期|共3页
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Mark L.Hlavinka; John R.Hagadorn;
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1. The First Structural Characterization of alpha-Zincated(Reformatsky)Amides and Phosphine Oxides [J] . Mark L.Hlavinka, John R.Hagadorn Organometallics . 2005,第17期

机译：α-锌（Reformatsky）酰胺和氧化膦的第一个结构表征
2. New thermally stable nanocomposites reinforced silicate nanoparticles containing phosphine oxide moiety based on poly(amide-imide): Synthesis, characterization and flame retardancy study [J] . Hajibeygi M., Shabanian M., Madani M. Journal of Polymer Research . 2013,第9期

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3. Clay-reinforced semi-aromatic polyether-amide namocomposites containing phosphine oxide moieties: synthesis and characterization [J] . Meisam Shabanian, Khalil Faghihi, Fatemeh Shabani Polymer bulletin . 2012,第2期

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4. Synthesis and Characterization of Polyimides from Bis(3-aminophenyl)-4-(1- adamantyl) Phenoxy Phenyl-phosphine Oxide (mDAATPPO) [C] . S. M. Kwak, J. H. Kim, Y. U. Bae PMSE Symposia . 2005

机译：来自双（3-氨基苯基）-4-（1-酰胺基）苯基磷酸氧化膦（MDAATPPO）的聚酰亚胺的合成与表征
5. Syntheses and characterizations of monomeric molybdenum(VI) complexes with bidentate phosphine oxide ligands and dimeric and tetrameric molybdenum(V) clusters with benzoic acid and phosphinic acid derivatives, containing molybdenum oxide, molybdenum(2) dioxide (mu-oxygen) and molybdenum(4) tetroxide (mu3-oxygen) structural motifs [D] . Sreehari, Soumyashree 2010

机译：具有二齿膦氧化物配体的单体钼（VI）配合物以及具有苯甲酸和次膦酸衍生物的二聚和四聚钼（V）簇的合成和表征，其中包含氧化钼，二氧化钼（mu-oxygen）和钼（4））四氧化物（mu3-氧）结构基序
6. Two tris(35-disubstituted phenyl)phosphines and their isostructural PV oxides [O] . Nathan D. D. Hill, René T. Boeré 2018

机译：两个三（35-二取代的苯甲酰基）膦及其同构结构PV氧化物
7. The First Structural Characterization of a-Zincated (Reformatsky) Amides and Phosphine Oxides [O] . -1

机译：镀锌（REPREATATSKY）酰胺和膦氧化物的第一结构表征
8. Structural Effects on Oxygen 17 NMR (Nuclear Magnetic Resonance) Shifts of Cyclic Phosphine Oxides [R] . Quin, L. D., Szewczyk, J., Linehan, K., 1987

机译：氧气的结构效应17核磁共振（核磁共振）循环的膦氧化物

The First Structural Characterization of alpha-Zincated(Reformatsky)Amides and Phosphine Oxides

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