A new and efficient method for the preparation of bismuthonium and telluronium salts using aryl- and alkenylboronic acids. First observation of the chirality at bismuth in an asymmetrical bismuthonium salt

Matano Y.; Miyamatsu T.; Suzuki H.; Begum SA.

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A new and efficient method for the preparation of bismuthonium and telluronium salts using aryl- and alkenylboronic acids. First observation of the chirality at bismuth in an asymmetrical bismuthonium salt

机译：一种使用芳基和烯基硼酸制备双bis和碲盐的新的有效方法。对不对称双曲铵盐中铋的手性的初步观察

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Treatment of triarylbismuth difluorides with aryl- and alkenylboronic acids in the presence of BF3. OEt2 afforded tetraaryl- and alkenyltriarylbismuthonium tetrafluoroborates, respectively, while similar treatment of diphenyltellurinyl difluoride yielded the corresponding telluronium salts. The chirality at bismuth was observed for the first time from the H-1 NMR spectrum of an asymmetrical bismuthonium salt. [References: 28]

机译：在BF3存在下，用芳基和烯基硼酸处理三氟化三芳基铋。 OEt2分别提供四氟硼酸四芳基酯和链烯基三芳基双ho四氟硼酸酯，而对二苯基碲灵二氟的类似处理得到相应的碲盐。从不对称双mut盐的H-1 NMR光谱中首次观察到铋的手性。 [参考：28]

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《Organometallics》 |1998年第20期|共3页
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Matano Y.; Miyamatsu T.; Suzuki H.; Begum SA.;
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正文语种 eng
中图分类有机化学;有机质材料;
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1. A new and efficient method for the preparation of bismuthonium and telluronium salts using aryl- and alkenylboronic acids. First observation of the chirality at bismuth in an asymmetrical bismuthonium salt [J] . Matano Y., Miyamatsu T., Suzuki H., Organometallics . 1998,第20期

机译：一种使用芳基和烯基硼酸制备双bis和碲盐的新的有效方法。对不对称双曲铵盐中铋的手性的初步观察
2. Synthesis and reaction of unsymmetrical tetraarylbismuthonium salts. First isolation of bismuthonium salts bearing all different aryl groups [J] . Matano Y., Suzuki H., Miyamatsu T. Chemistry Letters . 1998,第2期

机译：不对称四芳基双mut盐的合成和反应。首次分离带有所有不同芳基的双mut盐
3. Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium Salts [J] . Solyntjes Sven, Neumann Beate, Stammler Hans-Georg, European journal of inorganic chemistry . 2016,第25期

机译：二氟三有机基膦酸酯类用于合成氟phosph和铋盐
4. Development of Asymmetric Addition Reactions of Alkylazaareneswith Imines Using Chiral Metal Salt-Strong Base HybridCatalyst Systems [C] . Hyemin CHO, Aika NOGUCHI, YasuhiroYAMASHITA 日本化学会春季年会 . 2020

机译：使用手性金属盐 - 强碱杂交催化剂系统的烷基烷基亚胺酰亚胺的不对称添加反应的发展
5. Synthesis of chiral vinylsulfonium salts and their application in the synthesis of the mitomycin skeleton (Asymmetric epoxidation). [D] . Kim, Kyung Hee. 2001

机译：手性乙烯基s盐的合成及其在丝裂霉素骨架合成中的应用（不对称环氧化）。
6. Michael Addition Reactions between Chiral Equivalents of a Nucleophilic Glycine and (S)- or (R)-3-(E)-Enoyl-4-phenyl-13-oxazolidin-2-ones as a General Method for Efficient Preparation of β-Substituted Pyroglutamic Acids. Case of Topographically Controlled Stereoselectivity [O] . Vadim A. Soloshonok*, Chaozhong Cai, Takeshi Yamada, -1

机译：亲核甘氨酸与（S）-或（R）-3-（E）-烯丙基 -4-苯基-13-恶唑烷-2-酮的手性当量之间的迈克尔加成反应作为有效制备的一般方法β-取代的焦谷氨酸地形控制立体选择性的情况
7. A New Method of Generation of Bismuthonium Ylides and their Efficient Trapping with Sulphenes [O] . Ogawa Takuji, Murafuji Toshihiro, Suzuki Hitomi 2017

机译：生成铋铋盐的新方法及其对亚砜的有效捕集

A new and efficient method for the preparation of bismuthonium and telluronium salts using aryl- and alkenylboronic acids. First observation of the chirality at bismuth in an asymmetrical bismuthonium salt

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