New water-soluble alkyl-carbonyl iridium complexes containing both Cp* (C5Me5-) and PAr3 (P(m-C6H4SO3Na)(3)): Cleavage of C equivalent to C and C=C bonds with water

Chin CS.; Chong D.; Maeng B.; Ryu J.; Kim H.; Kim M.; Lee H.

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New water-soluble alkyl-carbonyl iridium complexes containing both Cp* (C5Me5-) and PAr3 (P(m-C6H4SO3Na)(3)): Cleavage of C equivalent to C and C=C bonds with water

机译：新型的同时包含Cp *（C5Me5-）和PAr3（P（m-C6H4SO3Na）（3））的水溶性烷基羰基铱铱配合物：裂解相当于水的C和C = C键

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Reactions of water-soluble Cp*IrCl2(PAr3) (1) with alkynes HCdropCR in H2O/C6H6 give new watersoluble alkyl-carbonyl complexes, [CP*Ir(-CH2R)(CO)-(PAr3)](+) (2, R = Ph (a), CH2Ph (b), C(CH3)(3) (c), p-C6H4CH3 (d)) by cleaving the CdropC bond of the alkynes. The Cdouble bondC bond of ethylene is also cleaved in the reaction of complex 1 with ethylene in the presence of Ag+ in water to give [Cp*Ir(-CH3)(CO)(PAr3)](+) (3). [References: 35]

机译：水溶性Cp * IrCl2（PAr3）（1）与炔烃HCdropCR在H2O / C6H6中的反应生成新的水溶性烷基羰基配合物[CP * Ir（-CH2R）（CO）-（PAr3）]（+）（2 ，R ＝ Ph（a），CH 2 Ph（b），C（CH 3）（3）（c），p-C 6 H 4 CH 3（d））通过裂解炔烃的CdropC键。在络合物1与乙烯在水中存在Ag +的情况下，乙烯的C双键C键也被裂解，得到[Cp * Ir（-CH3）（CO）（PAr3）]（+）（3）。 [参考：35]

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《Organometallics》 |2002年第8期|共4页
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Chin CS.; Chong D.; Maeng B.; Ryu J.; Kim H.; Kim M.; Lee H.;
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中图分类有机化学;有机质材料;
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1. New water-soluble alkyl-carbonyl iridium complexes containing both Cp* (C5Me5-) and PAr3 (P(m-C6H4SO3Na)(3)): Cleavage of C equivalent to C and C=C bonds with water [J] . Chin CS., Chong D., Maeng B., Organometallics . 2002,第8期

机译：新型的同时包含Cp *（C5Me5-）和PAr3（P（m-C6H4SO3Na）（3））的水溶性烷基羰基铱铱配合物：裂解相当于水的C和C = C键
2. [Cp*IrCl2](2)-assisted C equivalent to C bond cleavage with water: An experimental and computational study [J] . Sridevi VS, Fan WY, Leong WK Organometallics . 2007,第5期

机译：[Cp * IrCl2]（2）辅助的C等效于水裂解C键的实验和计算研究
3. Microwave synthesis of bis(tetrazolato)-Pd~(II) complexes with PPh_3 and water-soluble 1,3,5-triaza-7-phosphaadamantane (PTA). the first example of C-CN bond cleavage of propionitrile by a Pd~(II) Centre [J] . Lasri J., Fernández Rodríguez M.J., Guedes Da Silva M.F.C., Journal of Organometallic Chemistry . 2011,第22期

机译：微波合成具有PPh_3和水溶性1,3,5-triaza-7-phosphaadamantane（PTA）的双（四唑酮）-Pd〜（II）配合物。 Pd〜（II）中心丙腈C-CN键裂解的第一个例子
4. Water-soluble iridium phosphorescent complexes for OLED applications [C] . Min-Sik Eum, Heekoo Yoon, Tae Hyung Kim . 2012

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5. Catalytic C-C (C-N) Bond Formation and C-O Bond Cleavage by Pincer-Ligated Iridium Complexes [D] . Li, Bo. 2019

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6. Water-Soluble Iridium(III) Complexes Containing Tetraethylene-Glycol-Derivatized Bipyridine Ligands for Electrogenerated Chemiluminescence Detection [O] . Ben Newman, Lifen Chen, Luke C. Henderson, 2020

机译：水溶性铱（III）配合物含有四乙二醇衍生化的Bi0赖丁配体用于电化化学发光检测
7. Prediction of Irndash;H bond cleavage energies of cyclopentadienyl iridium complexes by DFT methods and their distortion-interaction analyses [O] . Yao Fu, Xudong He, Yuanye Jiang, 2016

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8. Preparation of B-sigma-Carboranyl Iridium Complexes by Oxidative Addition of Terminal Boron-Hydrogen Bonds to Iridium(I) Species. [R] . hoel, elvin l. hawthorne, m. f. 1975

机译：通过末端硼氢键与铱（I）物质的氧化加成制备B-sigma-Carboranyl Iridium配合物。

New water-soluble alkyl-carbonyl iridium complexes containing both Cp* (C5Me5-) and PAr3 (P(m-C6H4SO3Na)(3)): Cleavage of C equivalent to C and C=C bonds with water

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