Al-, Nb-, and Ta-based perfluoroaryloxide anions as cocatalysts for metallocene-mediated Ziegler-Natta olefin polymerization

Sun YM.; Stern CL.; Marks TJ.; Metz MV.

首页> 外文期刊>Organometallics >Al-, Nb-, and Ta-based perfluoroaryloxide anions as cocatalysts for metallocene-mediated Ziegler-Natta olefin polymerization

【24h】

Al-, Nb-, and Ta-based perfluoroaryloxide anions as cocatalysts for metallocene-mediated Ziegler-Natta olefin polymerization

机译：基于Al，Nb和Ta的全氟芳氧基阴离子作为茂金属介导的齐格勒-纳塔烯烃聚合的助催化剂

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Perfluoroaryloxide salts of the formula Ph3C+-Al(OC6F5)(4)(-) and Ph3C+M(OC6F5)(6)(-) (M = Nb, Ta) have been synthesized and characterized. In combination with sterically encumbered zirconocene dimethyl complexes, they yield active ethylene polymerization catalysts. [References: 39]

机译：合成并表征了式Ph3C + -Al（OC6F5）（4）（-）和Ph3C + M（OC6F5）（6）（-）（M = Nb，Ta）的全氟芳族盐。与空间上受阻的锆茂二甲基配合物结合，它们可制得活性乙烯聚合催化剂。 [参考：39]

著录项

来源
《Organometallics》 |2000年第9期|共3页
作者
Sun YM.; Stern CL.; Marks TJ.; Metz MV.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类有机化学;有机质材料;
关键词
Ion-pair structure; Group-4 metallocene; Molecular-structure; Catalysts; Zirconocene; Complexes; Reactivity; Cation; Ligand; Tetrakis(pentafluorophenyl)borate;

机译：离子对结构;4族茂金属;分子结构;催化剂;锆茂;复合物;反应性;阳离子;配体;四（五氟苯基）硼酸盐;

相似文献

外文文献
中文文献
专利

1. Al-, Nb-, and Ta-based perfluoroaryloxide anions as cocatalysts for metallocene-mediated Ziegler-Natta olefin polymerization [J] . Sun YM., Stern CL., Marks TJ., Organometallics . 2000,第9期

机译：基于Al，Nb和Ta的全氟芳氧基阴离子作为茂金属介导的齐格勒-纳塔烯烃聚合的助催化剂
2. Weakly coordinating Al-, Nb-, Ta-, Y-, and La-based perfluoroaryloxymetalate anions as cocatalyst components for single-site olefin polymerization [J] . Metz MV., Sun YM., Stern CL., Organometallics . 2002,第18期

机译：弱配位的Al-，Nb-，Ta-，Y-和La基全氟芳氧基金属酸盐阴离子作为单中心烯烃聚合的助催化剂组分
3. New organo-Lewis acids. Tris (beta-perfluoronaphthyl)borane (PNB) as a highly active cocatalyst for metallocene-mediated Ziegler-Natta alpha-olefin polymerization [J] . Li LT., Marks TJ. Organometallics . 1998,第18期

机译：新的有机路易斯酸。三（β-全氟萘基）硼烷（PNB）作为茂金属介导的齐格勒-纳塔α-烯烃聚合的高活性助催化剂
4. A novel consecutive chain transfer reaction to styrene and hydrogen during metallocene-mediated olefin polymerization [C] . J.Y.Dong, T.C.Chung PMSE Symposia . 2001

机译：茂金属介导的烯烃聚合过程中对苯乙烯和氢的一种新型连续链转移反应
5. New cocatalysts for Ziegler-Natta olefin polymerization. [D] . Metz, Matthew Vernon. 2002

机译：齐格勒-纳塔烯烃聚合的新型助催化剂。
6. Polymerization Special Feature: Nuclearity and cooperativity effects in binuclear catalysts and cocatalysts for olefin polymerization [O] . Hongbo Li, Tobin J. Marks 2006

机译：聚合特性：烯烃聚合的双核催化剂和助催化剂中的核化和协同作用
7. Nuclearity and cooperativity effects in binuclear catalysts and cocatalysts for olefin polymerization [O] . Li, Hongbo, Marks, Tobin J. 2006

机译：烯烃聚合的双核催化剂和助催化剂中的核化和协同作用效应

Al-, Nb-, and Ta-based perfluoroaryloxide anions as cocatalysts for metallocene-mediated Ziegler-Natta olefin polymerization

摘要

著录项

相似文献

相关主题

期刊订阅