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Electrodeposition of carbonate-containing hydroxyapatite on carbon nanotubes/carbon fibers hybrid materials for tissue engineering application

机译:碳纳米管/碳纤维混杂材料上含碳酸盐的羟基磷灰石的电沉积技术在组织工程中的应用

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Carbon nanotubes/carbon fibers hybrid materials (CCF) were used as templates to deposit carbonate-containing hydroxyapatite (CHA) by ultrasound-assisted electrodeposition method. The morphology and microstructure of CCF and CHA on CCF were characterized by X-ray diffraction, scanning electron microscopy, Transmission electron microscopy, Energy dispersive X-ray spectroscopy, Raman spectroscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and Thermogravimetric analysis. The results showed that the CCF was composed of carbon fibers and in situ grown carbon nanotubes. The carbon nanotubes were grown along the radial direction of the carbon fibers with a straight morphology and exhibited a loose structure. The CHA enwrapped the in situ grown carbon nanotubes of CCF, then infiltrated into the loose structures of the carbon nanotubes and finally covered the CCF entirely with a particle shape. By thermogravimetric analysis, the CHA on CCF displayed more deposition weight than that on carbon fibers without carbon nanotubes. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
机译:以碳纳米管/碳纤维杂化材料(CCF)为模板,通过超声辅助电沉积法沉积含碳酸盐的羟基磷灰石(CHA)。通过X射线衍射,扫描电子显微镜,透射电子显微镜,能量色散X射线光谱,拉曼光谱,傅立叶变换红外光谱,X射线光电子能谱和热重分析来表征CCF和CHA上CCF的形态和微观结构。结果表明,CCF由碳纤维和原位生长的碳纳米管组成。碳纳米管沿着碳纤维的径向方向以平直的形态生长,并显示出松散的结构。 CHA包裹了原位生长的CCF碳纳米管,然后渗透到碳纳米管的松散结构中,最后以颗粒形状完全覆盖了CCF。通过热重分析,与没有碳纳米管的碳纤维相比,CCF上的CHA沉积重量更大。 (C)2014 Elsevier Ltd和Techna Group S.r.l.版权所有。

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