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首页> 外文期刊>Russian journal of electrochemistry >Electrochemical and electrocatalytic properties of meso-triphenylcorrole and its complexes with Mn(III), Co(III), Cu(III), and Zn(II)1
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Electrochemical and electrocatalytic properties of meso-triphenylcorrole and its complexes with Mn(III), Co(III), Cu(III), and Zn(II)1

机译:介孔三苯甲醚及其与Mn(III),Co(III),Cu(III)和Zn(II)1的配合物的电化学和电催化性能

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摘要

The method of cyclic voltammetry (CV) was used to compare electrochemical and electrocatalytic properties of meso-triphenylcorrole [H3(ms-Ph)3Cor] and also its complexes with Mn(III), Co(III), Cu(III), and Zn(II) in 0.1M KOH. Metal-localized redox transitions are detected in the complexes of Mn (III → IV) and (III → II), Co (III → II), Cu (III → II). It is shown that the manganese complex features most effective catalytic properties in the reaction of molecular oxygen electroreduction.
机译:使用循环伏安法(CV)比较介孔三苯甲酚[H3(ms-Ph)3Cor]及其与Mn(III),Co(III),Cu(III)和在0.1M KOH中的Zn(II)。在Mn(III→IV)和(III→II),Co(III→II),Cu(III→II)的配合物中检测到金属局部氧化还原转变。结果表明,锰配合物在分子氧电化学还原反应中具有最有效的催化性能。

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