Direct borohydride oxidation electrocatalysts based on Ni-Ru/C and Ni-Ru-F/C alloys

Grinberg V.A.; Mayorova N.A.; Korlyukov A.A.; Pasynskii A.A.

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Direct borohydride oxidation electrocatalysts based on Ni-Ru/C and Ni-Ru-F/C alloys

机译：基于Ni-Ru / C和Ni-Ru-F / C合金的直接硼氢化物氧化电催化剂

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A fluorine-containing bimetallic nickel-ruthenium catalyst on highly disperse carbon black is synthesized based on an organometal nickel complex and a ruthenium cluster in the presence of perfluoroenanthic acid. The resulting catalyst is characterized by the XRD and energy-dispersion analyses and laser mass spectrometry. The overall composition of the catalytic system corresponds to Ni_(12)RuF_5. Calculated on the base of XRD data, the particle size is 10.5-12 nm. According to voltammetric data, the specific characteristics of the synthesized catalyst in the reaction of direct oxidation of sodium borohydride at room temperature surpass the characteristics of nickel-ruthenium catalyst described in the literature.

机译：在全氟庚酸存在下，基于有机金属镍配合物和钌簇，在高分散炭黑上合成了含氟双金属镍钌催化剂。所得催化剂通过XRD和能量色散分析以及激光质谱法表征。催化体系的总体组成相当于Ni_（12）RuF_5。根据XRD数据计算，粒径为10.5-12 nm。根据伏安数据，在室温下硼氢化钠直接氧化反应中合成催化剂的特定特性超过了文献中描述的镍钌催化剂的特性。

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《Russian journal of electrochemistry》 |2010年第11期|共8页
作者
Grinberg V.A.; Mayorova N.A.; Korlyukov A.A.; Pasynskii A.A.;
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正文语种 eng
中图分类电化学、电解、磁化学;
关键词
bimetallic catalyst; electrooxidation; organometal nickel complex; ruthenium cluster; sodium borohydride;

机译：双金属催化剂;电氧化;有机金属镍络合物;钌簇;硼氢化钠;

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1. Direct borohydride oxidation electrocatalysts based on Ni-Ru/C and Ni-Ru-F/C alloys [J] . Grinberg V.A., Mayorova N.A., Korlyukov A.A., Russian journal of electrochemistry . 2010,第11期

机译：基于Ni-Ru / C和Ni-Ru-F / C合金的直接硼氢化物氧化电催化剂
2. Evaluation of Colloidal Pd and Pd-alloys as Anode Electrocatalysts forDirect Borohydride Fuel Cells Applications [J] . M.H. Atwan, E.L. Gyenge, D.O. Northwood Journal of new materials for electrochemical systems . 2010,第1期

机译：胶体钯和钯合金作为直接电极用于硼氢化物燃料电池的阳极电催化剂的评估
3. Evaluation of colloidal Ag and Ag-alloys as anode electrocatalysts for direct borohydride fuel cells [J] . Mohammed H. Atwan, Derek O. Northwood, Elod L. Gyenge International journal of hydrogen energy . 2007,第15期

机译：胶态Ag和Ag合金作为直接硼氢化物燃料电池的阳极电催化剂的评估
4. Zinc-Cobalt Alloy Deposited on the Titanium Surface as Electrocatalysts for Borohydride Oxidation [C] . L. Tamasauskaite-Tamasiunaite, S. Lichusina, A. Balciunaite, Materials for low temperature electrochemical systems . 2014

机译：沉积在钛表面的锌钴合金作为硼氢化物氧化的电催化剂
5. Multifunctional oxidation electrocatalysts for direct alkaline fuel cells [D] . Martinez, Ulises. 2012

机译：直接碱性燃料电池的多功能氧化电催化剂
6. Facile Synthesis of PtCu Alloy/Graphene Oxide Hybridsas Improved Electrocatalysts for Alkaline Fuel Cells [O] . Taiyang Liu, Chaozhong Li, Qiang Yuan, 2018

机译：方便地合成PtCu合金/氧化石墨烯杂化物作为碱性燃料电池的改进电催化剂
7. Electrocatalyst design for direct borohydride oxidation guided by first principles [O] . Rostamikia, G., Patel, R. J., Merino-Jimenez, I., 2017

机译：由第一原理指导的直接氢硼化物氧化的电催化剂设计
8. New Electrocatalysts for Direct Oxidation of Organic Fuels [R] . Cairns, E. J., Reimer, J. A. 2009

机译：新型有机燃料直接氧化电催化剂

Direct borohydride oxidation electrocatalysts based on Ni-Ru/C and Ni-Ru-F/C alloys

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