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首页> 外文期刊>Scandinavian Journal of Metallurgy >A study on the purification of diatomite in hydrochloric acid
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A study on the purification of diatomite in hydrochloric acid

机译:盐酸中硅藻土的提纯工艺研究

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This paper describes the purification of diatomaceous earth mined in the Ankara region of Turkey. The diatomaceous earth was found to be essentially amorphous, but a small amount of crystalline illite, K_(0.7)Al_2(Si,Al)_4O_(10)(OH)_2, was present in it. The complete chemical composition of the material was 74.4 percent SiO_2, 14.55 percent Al_2O_3, 3.62 percent Fe_2O_3, 1.55 percent CaO, 1.37 percent MgO, 2.44 percent K_2O and 0.72 percent Na_2O. In connection with the purification of the diatomite, two different processing routes were planned: (i) leaching of the diatomaceous earth directly in cold acidic solutions of HCl; (ii) leaching of the diatomaceous earth directly by using hot 1 and 2N HCl. It was found that all of the undesirable elements in the composition of the diatomaceous earth were dissolved when treated at about 100 deg C with acidic solutions prepared using 1 and 2 N HCl for various leaching times. Under several cold acid concentrations, varying from 1 N to 5N HCl, however, only a small amount of silica is dissolved, while significantly reducing the contribution of undesirable aluminium, calcium, magnesium, iron and alkaline elements.
机译:本文介绍了土耳其安卡拉地区开采的硅藻土的提纯方法。发现硅藻土基本上是非晶态的,但是其中存在少量的结晶伊利石K_(0.7)Al_2(Si,Al)_4O_(10)(OH)_2。该材料的完整化学成分为74.4%SiO_2、14.55%Al_2O_3、3.62%Fe_2O_3、1.55%CaO,1.37%MgO,2.44%K_2O和0.72%Na_2O。与硅藻土的提纯有关,计划了两种不同的工艺路线:(i)直接在盐酸的冷酸性溶液中浸出硅藻土; (ii)用热的1N和2N HCl直接浸出硅藻土。发现在硅藻土组合物中所有不希望有的元素在用约1℃和2N HCl制备的酸性溶液在约100℃下处理各种浸出时间时都溶解了。但是,在几种从1 N到5N HCl的冷酸浓度下,仅溶解少量的二氧化硅,同时显着减少了不良的铝,钙,镁,铁和碱性元素的贡献。

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