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The elastic modulus of pure and doped ceria

机译:纯和掺杂二氧化铈的弹性模量

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摘要

Measurements of the elastic modulus of pure and doped ceria are summarized from the literature and analyzed with a view towards understanding the experimentally established dependence on temperature, doping level and oxygen vacancy concentration. At least two chemical properties affect the elastic modulus of pure and doped ceria: (i) the presence of vacancies decreases the strength of the chemical bonds;;and (ii) low-temperature adaptation of the fluorite structure to the presence of oxygen vacancies is accompanied by an increase in unit cell volume.
机译:从文献中总结了纯二氧化铈和掺杂二氧化铈的弹性模量,并进行了分析,以期了解实验确定的对温度,掺杂水平和氧空位浓度的依赖性。至少两个化学性质会影响纯和掺杂二氧化铈的弹性模量:(i)空位的存在会降低化学键的强度;并且(ii)萤石结构对氧空位的低温适应性是伴随着晶胞体积的增加。

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