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Removal of disinfection by-products precursors by polyaluminum chloride coagulation coupled with chlorination

机译:聚氯化铝混凝加氯去除消毒副产物前体

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The effect of coagulation coupled with chlorination (i.e., pre-, inter-, and post-chlorination) on the formation of disinfection by-products (DBPs) and the removal efficiency of DBPs precursors were investigated. Compared with coagulation coupling with pre-chlorination, coagulation coupled with inter-chlorination could lead a higher removal efficiency of dissolved organic carbon (DOC), specific ultraviolet absorbance (SUVA) and chloroacetic acids formation potential (CAAsFP). The CAAsFP/DOC value of residual DOC showed that coagulation with inter-chlorination has a beneficial effect on CAAs precursors removal. More DBPs were produced during inter-chlorination than that of pre-chlorination at pH 7.5, while less DBPs were produced during inter-chlorination than that of pre-chlorination at pH 5.5. In addition, the precipitate of humic acid (HA) after coagulation was chlorinated to study the kinetics of chlorine decay. The results showed that coagulated-HA had a higher reactivity with chlorine than aqueous-HA at pH 7.5. Furthermore, the trends of zeta potential during coagulation process suggested that the distribution of chlorine species had significant influence on the removing of DBPs precursors by coagulation coupled with chlorination.
机译:研究了混凝与氯化反应(即氯化前,氯化间和氯化后)对消毒副产物(DBPs)形成和DBPs前体去除效率的影响。与采用预氯化的混凝相比,采用混氯化的混凝可以提高溶解有机碳(DOC),比紫外线吸收率(SUVA)和氯乙酸形成潜力(CAAsFP)的去除效率。残留DOC的CAAsFP / DOC值表明,氯化间混凝对CAA前体的去除具有有益作用。在pH值为7.5时,氯化间生成的DBP比预氯化的要多,而在pH值为5.5时,氯化间生成的DBP少。此外,对凝结后的腐殖酸(HA)沉淀物进行了氯化处理,以研究氯衰减的动力学。结果表明,在pH 7.5时,凝结的HA与氯的反应性比含水的HA高。此外,在凝结过程中ζ电位的趋势表明,氯物种的分布对凝结和氯化作用对DBPs前体的去除有显着影响。

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