Purification of neutron-irradiated tellurium targets from cross-radiocontaminants by precipitation with 1,10-phenanthroline

M. Mostafa

首页> 外文期刊>Separation and Purification Technology >Purification of neutron-irradiated tellurium targets from cross-radiocontaminants by precipitation with 1,10-phenanthroline

【24h】

Purification of neutron-irradiated tellurium targets from cross-radiocontaminants by precipitation with 1,10-phenanthroline

机译：通过1,10-菲咯啉沉淀法纯化交叉辐射污染物中的中子辐照碲靶

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Irradiated tellurium targets were purified by precipitation from 6M HCl solution using 1,10-phenanthroline. The effect of molar ratio of the reactants (initial 1,10-phenanthroline:Te molar ratio) on the precipitation yield of radiotellurium was studied. It was found that, >99% of radiotellurium has been taken up by the precipitate formed with the initial 2 phenanthroline:lTe molar ratio along with different decontamination ratios from the other cross-radiocontaminants; ≥99.9% of ~(65)Zn, 97.7 ± 1.2% of ~(75)Se, ≥99.9% ~(110m)Ag, and 95.4 ±2.5% of ~(124)Sb. Traces of ~(51)Cr, ~(54)Mn, ~(59)Fe, and ~(60)Co have been detected only in the supernatant after the precipitation process. Un-irradiated tellurium was precipitated with 1,10-phenanthroline under the same conditions with the initial 2phenanthroline:lTe molar ratio and, then, the precipitate formed was characterized by IR spectroscopy and thermal analysis. The most probable chemical composition of this precipitate was [Te(phen)2Cl4]·3.4H2O.

机译：通过使用1,10-菲咯啉从6M HCl溶液中沉淀纯化辐照的碲靶。研究了反应物的摩尔比（初始的1,10-菲咯啉：Te摩尔比）对放射性碲沉淀率的影响。发现，最初的2菲咯啉：1Te摩尔比以及与其他交叉放射性污染物不同的去污率所形成的沉淀物已吸收了超过99％的放射性碲。〜（65）Zn的≥99.9％，〜（75）Se的97.7±1.2％，〜（110m）Ag的≥99.9％和〜（124）Sb的95.4±2.5％。在沉淀过程之后，仅在上清液中检测到痕量的〜（51）Cr，〜（54）Mn，〜（59）Fe和〜（60）Co。在相同的条件下，以初始的2菲咯啉∶1Te摩尔比，在未辐照的碲条件下用1,10-菲咯啉沉淀，然后通过红外光谱和热分析对形成的沉淀进行表征。该沉淀物最可能的化学组成是[Te（phen）2Cl4]·3.4H2O。

著录项

来源
《Separation and Purification Technology》 |2008年第2期|共9页
作者
M. Mostafa;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类分离过程;
关键词
Radiotellurium; Tellurium dioxide; 1; 10-Phenanthroline; Precipitation; Purification; Radiocontaminants;

机译：放射性碲;二氧化碲;1;10-菲咯啉;沉淀;纯化;放射性污染物;

相似文献

外文文献
中文文献
专利

1. Purification of neutron-irradiated tellurium targets from cross-radiocontaminants by precipitation with 1,10-phenanthroline [J] . M. Mostafa Separation and Purification Technology . 2008,第2期

机译：通过1,10-菲咯啉沉淀法纯化交叉辐射污染物中的中子辐照碲靶
2. A Novel 1:1 Co-Crystal of Bis(1,10-Phenanthroline)(1,10-Phenanthroline-5,6-Dione)Nickel(II) Hexafluorophosphate and Tris(1,10-Phenanthroline)Nickel(II) Hexafluorophosphate Complexes, [Ni(phen)₂(phen-dione)] [Ni(phen)₃] (PF₆)₄ [J] . Journal of Chemical Crystallography . 2012,第5期

机译：双（1,10-邻菲咯啉）（1,10-菲咯啉-5,6-二酮）镍（II）六氟磷酸盐和三（1,10-菲咯啉）镍（II）六氟磷酸盐配合物的新型1：1共晶，[Ni（phen）_{2 （phen-dione）] [Ni（phen）_{3 ]（PF _{6 ）_{4 < / sub>}}}}
3. Displacement reactions of 2-chloro-and 2,9-dichloro-1,10-phenanthroline: synthesis of a sulfur-bridged bis-1,10-phenanthroline macrocycle and a 2,2-amino-substituted-bis-1,10-phenanthroline [J] . A. Paul Krapcho, Silvia Sparapani, Amber Leenstra Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2009,第26期

机译：2-氯和2,9-二氯-1,10-菲咯啉的置换反应：硫桥联的bis-1,10-菲咯啉大环和2,2-氨基取代的bis-1,10-的合成菲咯啉
4. Study of the complexation reactions between dichloro-substituted 1,10- phenanthroline-2,9-dicarboxamide and lanthanide nitrates [C] . Ts. Sumyanova, N. Borisova, D. Volkova, Saratov Meeting: Laser Physics, Photonic Technologies, and Molecular Modeling . 2020

机译：二氯取代的1,10-膦腈-2,9-二羧酰胺和镧硝酸盐之间的络合反应研究
5. The Luminescent Properties of Europium Thenoyltrifluoroacetone Complexes with 2-Phenyl-1h-Imidazo[4,5-f][1,10]Phenanthroline Based Ligands [D] . Venturo, Paul Jacob. 2020

机译：铕的发光特性罗霉氟丙酮配合物用2-苯基-1H-咪唑络合物[4,5-F] [1,10]菲芳啉基配体
6. 1,10-Phenanthrolinium 4-chloro-2-hydroxybenzoate–1,10-phenanthroline–4-chloro-2-hydroxybenzoic acid (1/1/1) [O] . Hong Shen, Jing-Jing Nie, Duan-Jun Xu 2015

机译：1,10-菲咯啉4-氯-2-羟基苯甲酸–1,10-菲咯啉–4-氯-2-羟基苯甲酸（1/1/1）
7. 1,10-Phenanthrolin-1-ium nitrate–aquabis(4-hydroxybenzoato-κ2O,O′)(nitrato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)erbium(III)–1,10-phenanthroline–water (1/1/0.5/2) [O] . Shie Fu Lush, Fwu Ming Shen 2011

机译：1,10-菲咯啉-1-硝酸盐＆amp;＃aquabis（4-羟基苯甲酸 - ＆＃954; 2O，O＆＃8242）（硝酸盐＆＃954; 2O，＆＃8242））（ 1,10-菲咯啉 - ＆＃954; 2N，N＆＃8242;）铒（III）＆＃8211; 1,10-菲咯啉＆＃8211;水（1/1 / 0.5 / 2）

Purification of neutron-irradiated tellurium targets from cross-radiocontaminants by precipitation with 1,10-phenanthroline

摘要

著录项

相似文献

相关主题

期刊订阅