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Liquid-liquid equilibrium of the Ucon 50-HB5100/sodium citrate aqueous two-phase systems

机译:Ucon 50-HB5100 /柠檬酸钠水两相系统的液-液平衡

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摘要

The phase diagrams of Ucon 50-HB5100/sodium citrate aqueous two-phase systems were determined at 5, 20 and 40 °C. Two medium pHs 5.20 and 8.20 were assayed. The binodal curves were satisfactorily described using a four-parameter sigmoidal equation. The two-phase area was expanded by increasing both pH and temperature. The reliability of the measured tie line compositions was ascertained by correlation equations given by Othmer-Tobias and Bancroft.
机译:在5、20和40°C下确定Ucon 50-HB5100 /柠檬酸钠水两相系统的相图。测定了两种中等pH 5.20和8.20。使用四参数S形方程令人满意地描述了双曲线曲线。通过增加pH和温度来扩大两相区域。通过Othmer-Tobias和Bancroft给出的相关方程确定了测得的联络线成分的可靠性。

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