Kinetics of acrylonitrile adsorption from an aqueous solution using Dowex Optipore L-493

C. Wegmann; E. Suarez Garcia; P.J.A.M. Kerkhof

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Kinetics of acrylonitrile adsorption from an aqueous solution using Dowex Optipore L-493

机译：使用Dowex Optipore L-493从水溶液中吸附丙烯腈的动力学

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Adsorption is widely applied in water treatment and activated carbon is the most common adsorbent. Slow intraparticle mass transfer and incomplete regeneration of the activated carbon form drawbacks in adsorption processes. Recently the use of polymeric sorbents as an alternative for activated carbon has been increasing. In this study the kinetics of the adsorption of acrylonitrile from an aqueous solution onto Dowex Optipore L-493, a polymeric sorbent, is examined using zero-length columns. The adsorption equilibrium was found by use of batch experiments and it could be described by a Langmuir isotherm. The external mass transfer was estimated by use of correlations. The intraparticle surface diffusion coefficient was found to be 2.0 x 10~(-10) m~2/s. The fast intraparticle mass transfer allows running adsorption columns with a high superficial velocity which is desirable for industrial processes.

机译：吸附被广泛应用于水处理中，活性炭是最常见的吸附剂。缓慢的颗粒内传质和活性炭的不完全再生在吸附过程中形成了缺陷。最近，越来越多地使用聚合物吸附剂作为活性炭的替代品。在这项研究中，使用零长度色谱柱检查了丙烯腈从水溶液中吸附到聚合物吸附剂Dowex Optipore L-493上的动力学。吸附平衡是通过分批实验发现的，可以用Langmuir等温线描述。通过使用相关性估算外部传质。发现颗粒内表面扩散系数为2.0×10〜（-10）m〜2 / s。快速的颗粒内质量传递使吸附柱能够以较高的表观速度运行，这对于工业过程而言是理想的。

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《Separation and Purification Technology》 |2011年第3期|共6页
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C. Wegmann; E. Suarez Garcia; P.J.A.M. Kerkhof;
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Acrylonitrile; Adsorption; Intraparticle diffusion coefficient; Liquid film mass transfer coefficient; Polymeric sorbent;

机译：丙烯腈吸附颗粒内扩散系数液膜传质系数聚合物吸附剂;

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1. Kinetics of acrylonitrile adsorption from an aqueous solution using Dowex Optipore L-493 [J] . C. Wegmann, E. Suarez Garcia, P.J.A.M. Kerkhof Separation and Purification Technology . 2011,第3期

机译：使用Dowex Optipore L-493从水溶液中吸附丙烯腈的动力学
2. Equilibrium and kinetics studies on adsorption of Zn(II) from aqueous solutions onto a graft copolymer of cross-linked starch/acrylonitrile (CLSAGCP) [J] . Zhang YJ, Chen JR, Yan XY Colloids and Surfaces, A. Physicochemical and Engineering Aspects . 2008,第1a3期

机译：水溶液中Zn（II）吸附在交联淀粉/丙烯腈接枝共聚物（CLSAGCP）上的平衡和动力学研究
3. Equilibrium and kinetics studies on adsorption of Cu(II) from aqueous solutions onto a graft copolymer of cross-linked starch/acrylonitrile (CLSAGCP) [J] . Zhang YJ, Chen JR, Yan XY, The Journal of Chemical Thermodynamics . 2007,第6期

机译：水溶液中Cu（II）吸附在交联淀粉/丙烯腈接枝共聚物（CLSAGCP）上的平衡和动力学研究
4. Study on copper(Ⅱ)adsorption from an aqueous solution by the graft copolymer of cross-linked starch/acrylonitrile [C] . Yu-jun ZHANG, Jing-bo HU, Xiang-yang YAN, The International Conference on Advances in Chemical Technologies for Water and Wastewater Treatment(2008年化学技术对水及废水处理国际研讨会)论文集 . 2008

机译：交联淀粉/丙烯腈接枝共聚物从水溶液中吸附铜（Ⅱ）的研究
5. I. THE ELECTROCHEMISTRY OF NITRIC OXIDE AND A NITROUS ACID AT A MERCURY ELECTRODE IN AQUEOUS SOLUTIONS. II. ELECTROCHEMISTRY AND HYDROLYSIS KINETICS OF THE 2,2'-BIPYRIDINE COMPLEXES OF IRON(III) AND IRON(II); ELECTROCHEMICAL KINETIC PARAMETERS FOR SEVERAL IRON COMPLEXES. III. PROTON NUCLEAR MAGNETIC RESONANCE STUDIES OF URANIUM(IV)-ETHYLENE DIAMINETETRAACETIC ACID COMPLEXES IN AQUEOUS (DEUTERIUM-OXIDE) SOLUTIONS. [D] . EHMAN, DEWAYNE LEE. 1969

机译：I.水溶液中汞电极上一氧化二氮和亚硝酸的电化学二。铁（III）和铁（II）的2,2'-联吡啶络合物的电化学和水解动力学；多种铁络合物的电化学动力学参数。三，铀（IV）-水溶液（氧化氘）中铀（IV）-乙撑双氨基乙酸复合物的质子核磁共振研究
6. Simultaneous Adsorption of Cationic Dyes from Binary Solutions by Thiourea-Modified Poly(acrylonitrile-co-acrylic acid): Detailed Isotherm and Kinetic Studies [O] . Abel Adekanmi Adeyi, Siti Nurul Ain Md Jamil, Luqman Chuah Abdullah, 2019

机译：硫脲改性的聚（丙烯腈-共丙烯酸）同时吸附二元溶液中的阳离子染料：详细的等温线和动力学研究
7. Removing of Anionic Dye from Aqueous Solutions by Adsorption Using of Multiwalled Carbon Nanotubes and Poly (Acrylonitrile-styrene) Impregnated with Activated Carbon [O] . Khamael M. Abualnaja, Ahmed E. Alprol, M. A. Abu-Saied, 2021

机译：用多壁碳纳米管的吸附除去水溶液的阴离子染料，用活性炭浸渍的多晶碳纳米管和聚（丙烯腈 - 苯乙烯）
8. Proton Adsorption at the Ferric Oxide/Aqueous Solution Interface. I. A Kinetic Study of Adsorption. [R] . Onoda, G. Y. 1965

机译：质子在氧化铁/水溶液界面上的吸附。 I.吸附动力学研究。

Kinetics of acrylonitrile adsorption from an aqueous solution using Dowex Optipore L-493

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