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Preparation of hydrophilic poly(vinyl butyral)/Pluronic F127 blend hollow fiber membrane via thermally induced phase separation

机译:热诱导相分离法制备亲水性聚乙烯醇缩丁醛/ Pluronic F127共混中空纤维膜

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摘要

Polyvinyl butyral) (PVB)/surfactant with high molecular weight (Pluronic F127) blend hollow fiber membranes were prepared via thermally induced phase separation (TIPS) from PVB/Pluronic F127/diluent (PEG200) system. The phase diagram of PVB/PEG200 system was obtained and the addition of Pluronic F127 to this system led to the decrease of the cloud point. In order to know the kinetic property in the membrane preparation process, a light scattering experiment was carried out in cooling process of the PVB solution. The result indicated that the initial interphase periodic distance formed from the phase separation of PVB/Pluronic F127/PEG200 system was smaller than that of PVB/PEG200 system and its growth rate was lower in the former system. The properties of the hollow fiber membranes such as water permeability, particle rejection and hydrophilicity were investigated. The air gap distance in the membrane preparation condition highly influenced the water permeability.
机译:通过热诱导相分离(TIPS)从PVB / Pluronic F127 /稀释剂(PEG200)系统制备具有高分子量的聚乙烯醇缩丁醛(PVB)/表面活性剂(Pluronic F127)共混中空纤维膜。获得了PVB / PEG200系统的相图,向该系统中添加Pluronic F127导致浊点降低。为了了解膜制备过程中的动力学性质,在PVB溶液的冷却过程中进行了光散射实验。结果表明,由PVB / Pluronic F127 / PEG200系统的相分离形成的初始相间周期性距离小于PVB / PEG200系统的相间周期性距离,并且在前一个系统中其生长速率较低。研究了中空纤维膜的透水性,颗粒截留率和亲水性等性能。膜制备条件下的气隙距离对透水性有很大影响。

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