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Dissolution of model coal minerals (gypsum and pyrite) in RuCl_3 solution--a demineralisation approach

机译:模型煤矿物(石膏和黄铁矿)在RuCl_3溶液中的溶解-一种脱矿质方法

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摘要

Gypsum accounts for sulfate sulfate sulfur and pyrite for pyritic sulfur, are occurring in coal; dissolution of their model samples were carried out using RuCl_3 solution. The extent of soluble calcium from gypsum at 25 deg C and 3.90-6.31% at 80 deg C in the same time period. The rate constants for gypsum dissolution are exceedingly higher (1,12-4.23)10~-3 s~-1, than those observed for pyrite, (1.58-3.92)10~-6s~-1. It is observed that RuCl)3 is a suitable reagent for the removal of gypsum by dissolution process.
机译:石膏占煤中的硫酸根,硫酸根和黄铁矿。使用RuCl_3溶液进行模型样品的溶解。在同一时间段内,石膏在25摄氏度时的可溶性钙含量和在80摄氏度时的3.90-6.31%。石膏的溶解速率常数(1,12-4.23)10〜-3 s-1 -1比黄铁矿的速率常数(1.58-3.92)10〜-6s-1 -1高得多。观察到RuCl 3是适合于通过溶解过程除去石膏的试剂。

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