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Separation of ethanol-water solution by poly(acrylonitrile-co-acrylic acid)membranes

机译:聚丙烯腈-丙烯酸共聚物膜分离乙醇-水溶液

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摘要

The separation of an ethanol-water solution by steady-state pervaporation was investigated.Poly(acrylonitrile-co-acrylic acid)was prepared and used as a membrane.The permeate flux and separation factor were measured over the full range of ethanol-water composition at temperatures 30,40 and 50 deg C.Pervaporation exhibited negative deviations from ideal pervaporation behavior and the separation factors obtained varied from 5.4 to 31,depending on the composition of the feed mixture,and the temperature and the content of acrylic acid(AA)in copolymer membrane.Water clustering and strong water-alcohol interaction within the copolymer membrane can be considered in interpreting the observed pervaporation and selectivity.
机译:研究了稳态渗透蒸发分离乙醇-水溶液的方法,制备了聚丙烯腈-丙烯酸共膜并用作膜,在整个乙醇-水成分范围内测量了渗透通量和分离系数。在30,40和50摄氏度的温度下,全汽化与理想的全汽化表现出负偏差,分离系数从5.4到31不等,取决于进料混合物的组成,温度和丙烯酸(AA)的含量在解释观察到的渗透蒸发和选择性时,可以考虑水的聚集和共聚物膜内强烈的水-醇相互作用。

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