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Use of hydrometallurgical wastewater as a precursor for the synthesis of cryptomelane-type manganese dioxide ion exchange material

机译:湿法冶金废水作为合成隐甲烷型二氧化锰离子交换材料的前体

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摘要

Cryptomelane-type manganese dioxide was synthesized in order to use it as ion exchange material for the removal of heavy metals from wastewaters. The synthesis was carried out using hydrometallurgical wastewater simulant that is very typical for mining industry after sulphuric acid leaching of the ore and the recovery of base metals. This raffinate simulant solution, consisting of Al, Fe, Mg, Mn, Ca and Na was used as precursor and pure cryptomelane-structured manganese dioxide was synthesized. The ion exchange properties of the cryptomelane were typical for weakly acidic ion exchangers with selectivity towards transition metals. The obtained capacity of 1.3 mmol/g for copper and distribution coefficient as high as ~10~4 ml/g are promising for future applications in metal separation processes.
机译:合成了隐甲烷型二氧化锰,以将其用作离子交换材料以去除废水中的重金属。使用湿法冶金废水模拟剂进行合成,这对于矿石的硫酸浸出和贱金属的回收是采矿业非常典型的。以铝,铁,镁,锰,钙和钠组成的残液模拟溶液为前驱体,合成了隐甲烷结构的纯二氧化锰。隐甲烷的离子交换特性是弱酸性离子交换剂的典型特征,对过渡金属具有选择性。所获得的1.3 mmol / g的铜容量和高达〜10〜4 ml / g的分配系数对于金属分离工艺的未来应用前景广阔。

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