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Synthesis and water vapor separation properties of pure silica and aluminosilicate MCM-48 membranes

机译:纯二氧化硅和铝硅酸盐MCM-48膜的合成及水蒸气分离特性

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This work reports on the hydrothermal synthesis and gas-vapor separation properties of ordered meso-porous MCM-48 and Al-MCM-48 membranes. Gas permeation data for these membranes is characterized by the Knudsen type permeation mechanism, with a helium permeance of 7 x 10~(-8) mol/m~2 Pas and 3 x 10~(-8) mol/m~2 Pas, respectively, confirming the mesoporous nature of the membranes synthesized. Separation of a water vapor/oxygen mixture for these membranes was studied to explore potential use of these membranes in air dehumidification and air conditioning applications. These membranes offer high water vapor/oxygen selectivity as a result of capillary condensation of water vapor in the pores of the membranes. In the case of MCM-48, an oxygen permeance of 5 x 10~(-9) mol/m~2 Pa s is obtained, with a water permeance of around 1 x 10~(-7) mol/m~2 Pas. The water vapor/oxygen separation factors as high as 17 are achieved. Al-MCM-48 membranes are seen to provide much higher separation factors reaching as high as 142, with water vapor permeance of 6 x 10~(-8) mol/m~2 Pas.
机译:这项工作报告了有序中孔MCM-48和Al-MCM-48膜的水热合成和气水分离特性。这些膜的气体渗透数据以Knudsen型渗透机理为特征,氦气渗透率为7 x 10〜(-8)mol / m〜2 Pas和3 x 10〜(-8)mol / m〜2 Pas,分别证实了合成膜的介孔性质。研究了用于这些膜的水蒸气/氧气混合物的分离,以探索这些膜在空气除湿和空调应用中的潜在用途。由于水蒸汽在膜孔中的毛细管冷凝作用,这些膜具有高的水蒸气/氧气选择性。在MCM-48的情况下,氧气渗透率为5 x 10〜(-9)mol / m〜2 Pas,水渗透率为1 x 10〜(-7)mol / m〜2 Pas左右。达到高达17的水蒸气/氧气分离系数。 Al-MCM-48膜可提供更高的分离因子,高达142,水蒸气渗透率为6 x 10〜(-8)mol / m〜2 Pas。

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