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Ultrasonic degradation of reactive brilliant red K-2BP in water with CCl4 enhancement: Performance optimization and degradation mechanism

机译:超声降解CCl4增强水中活性艳红K-2BP的性能优化和降解机理

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摘要

The ultrasonic degradation of reactive brilliant red K-2BP (K-2BP) in water with CCl4 enhancement was investigated. The effects of operating parameters, such as CCl4 dosage, ultrasonic power, media temperature, dye initial concentration, and initial media pH on K-2BP degradation were discussed. The ultrasonic degradation of K-2BP was obviously enhanced by CCl4 addition—an effect attributed to the increased ~·OH radical concentration in the presence of CCl4 as a hydrogen atom scavenger, and the formation of chlorine-containing radicals. The main degradation products of K-2BP were tentatively identified by GC-MS and ion chromatography. A possible degradation pathway for K-2BP was also proposed.
机译:研究了CCl4增强对水中活性艳红K-2BP(K-2BP)的超声降解。讨论了CCl4用量,超声功率,介质温度,染料初始浓度和初始pH值等操作参数对K-2BP降解的影响。添加CCl4明显增强了K-2BP的超声降解-这种作用归因于在存在作为氢原子清除剂的CCl4的情况下〜·OH自由基浓度增加和含氯自由基的形成。通过GC-MS和离子色谱法初步鉴定出K-2BP的主要降解产物。还提出了K-2BP可能的降解途径。

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