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Permeation and sorption properties of poly(ether-block-amide) membranes filled by two types of zeolites

机译:两种沸石填充的聚(醚嵌段酰胺)膜的渗透和吸附性能

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摘要

The experimental study of transport properties of mixed matrix membranes (MMMs) based on PEBA-4033 with two types of zeolites is reported. Gas (CO2, O2, N2) and vapor (benzene, toluene, methanol, water) permeation measurements were performed using the differential flow permeameter at temperature of 298.15 K and at atmospheric pressure. Gas/vapor permeation was monitored by measuring the changes of the thermal conductivity of carrier gas (H2). Sorption experiments were performed gravimet-rically. Determined values of the transport parameters (permeability, diffusion and sorption coefficients) of all studied vapors revealed expected high-order permeability of PEBA based membranes for vapors in comparison with gases whereas increasing of zeolite-filler content up to 30 wt.% in polymer matrix led to higher values of permeability and gas/gas and vapor/gas selectivity in comparison with pure polymer.
机译:报道了基于PEBA-4033和两种沸石的混合基质膜(MMM)传输特性的实验研究。气体(CO 2,O 2,N 2)和蒸气(苯,甲苯,甲醇,水)的渗透率测量是使用差分流量渗透仪在298.15 K的温度和大气压下进行的。通过测量载气(H2)的热导率变化来监测气体/蒸汽的渗透。吸附实验通过重力进行。所有研究蒸气的传输参数(渗透率,扩散系数和吸附系数)的确定值表明,与气体相比,PEBA基膜对蒸气的预期高渗透率,而在聚合物基质中沸石填料的含量增加到30 wt。%与纯聚合物相比,导致较高的渗透率,气体/气体和蒸汽/气体选择性值。

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