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Improvement in diesel desulfurization capacity by equilibrium isotherms analysis

机译:通过平衡等温线分析提高柴油的脱硫能力

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Mesoporous aluminosilicates (MAS) showed advantages over zeolites and mesoporous molecular sieves in adsorption desulfurization of diesel fuels. However, the adsorptive capacity still has great space to improve. The equilibrium adsorption data were modeled by Langmuir and Freundlich isotherms. Lang-muir model can well describe the adsorption on ion-exchanged MAS. Infer from the hypothesis conditions of Langmuir model, the temperature and the active sites are two key factors to determine the adsorptive capacity. Adsorption experiments were carried out with both model oils and diesel fuels on fixed-bed. The results showed that π-complexation adsorbents were more efficient to remove sulfur compounds at higher temperature and that the saturated adsorption capacity had a linear relationship with the silver ions loaded on the adsorbents.
机译:介孔铝硅酸盐(MAS)在吸附和脱硫柴油中比沸石和介孔分子筛更具优势。但是,吸附能力仍有很大的提高空间。平衡吸附数据由Langmuir和Freundlich等温线建模。 Lang-muir模型可以很好地描述离子交换MAS的吸附。从Langmuir模型的假设条件推断,温度和活性位点是决定吸附能力的两个关键因素。在固定床上对模型油和柴油进行了吸附实验。结果表明,π-络合吸附剂在较高温度下去除硫化合物的效率更高,饱和吸附容量与吸附在吸附剂上的银离子呈线性关系。

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