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Absorption of carbon dioxide with piperazine and its mixtures in a rotating packed bed

机译:哌嗪及其混合物在旋转填充床中吸收二氧化碳

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The removal efficiency of carbon dioxide from gases containing 10% CO_2 by the aqueous solutions containing piperazine(PZ)and its mixture with monoethanolamine(MEA),2-amino-2-methyl-l-propanol(AMP),and methyldiethanolamine(MDEA)in a rotating packed bed was investigated in this study.The efficiency was assessed in terms of an overall volumetric mass transfer coefficient(K_Ga)that was found to be a strong function of gas and liquid flow rates.The obtained results indicated that PZ was the most effective absorbent over MEA,AMP,and MDEA.This was attributed to a high reaction rate of PZ with CO_2.The mixed amines containing PZ and MEA as well as PZ and AMP exhibited a high CO_2 removal efficiency as well.A higher portion of PZ in the mixture was more favorable to CO_2 absorption.The mixture of PZ with MDEA,however,was found not to be appropriate due to a low reaction activity of MDEA with CO_2.The CO_2 removal efficiency in a rotating packed bed was also observed to be more effective than that in a packed tower,implying a great potential of a rotating packed bed applied to the reduction of the greenhouse gas CO_2 from the exhausted gases.
机译:含哌嗪(PZ)及其与单乙醇胺(MEA),2-氨基-2-甲基-1-丙醇(AMP)和甲基二乙醇胺(MDEA)的混合物从含10%CO_2的气体中去除二氧化碳的效率本研究以旋转填充床为研究对象,以总体积传质系数(K_Ga)作为气体和液体流速的强函数来评估效率,所得结果表明PZ为这是PZ与CO_2的高反应速率所致,是MEA,AMP和MDEA上最有效的吸收剂.PZ和MEA以及PZ和AMP的混合胺也具有较高的CO_2去除效率。混合物中的PZ更加有利于CO_2的吸收。但是,由于MDEA与MD_2的反应活性低,因此发现PZ与MDEA的混合物不合适,还观察到旋转填充床中的CO_2去除效率为比t更有效在填充塔中安装一个帽子,这意味着旋转填充床具有很大的潜力,可用于减少废气中的温室气体CO_2。

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